55337-55-8Relevant articles and documents
Visible-light-promoted oxidative coupling of styrene with cyclic ethers
Kibriya, Golam,Ghosh, Debashis,Hajra, Alakananda
, p. 42 - 46 (2019/11/11)
A new visible-light-promoted oxidative coupling of vinylarenes with cyclic ethers has been developed using rose bengal as photocatalyst and tert-butyl hydrogenperoxide (TBHP) as oxidant under ambient air at room temperature. A library of α-oxyalkylated ketones with broad functionalities has been synthesized in moderate to good yields. A radical mechanism is suggested for the present protocol.
Regioselective oxyalkylation of vinylarenes catalyzed by diatomite-supported manganese oxide nanoparticles
Sun, Huayin,Zhang, Yonghui,Guo, Fengfeng,Zha, Zhenggen,Wang, Zhiyong
experimental part, p. 3563 - 3569 (2012/05/20)
A regioselective oxyalkylation reaction of vinylarenes with cyclic ethers was developed under the catalysis of a new heterogeneous catalyst, the diatomite-supported Mn3O4 nanoparticles (SMONP-1). The use of this heterogeneous catalyst provided a novel approach for the synthesis of α-carbonyled β-alkylated aryl derivatives via a sp3 C-H bond functionalization under mild aerobic conditions.
First reference to the alkoxymetallation of diisobutylaluminium and bromomagnesium-2-vinyloxy ethoxide to the corresponding (1,3-dioxolan-2- yl)methyl organometallics
Maier, Peter,Redlich, Hartmut
, p. 257 - 259 (2007/10/03)
Diisobutylaluminium and bromomagnesium-2-vinyloxy-ethoxide add at carbonyl compounds in the manner of (1,3-dioxolan-2-yl)methyl organometallics, giving the carbon-carbon addition products. It is assumed that the aluminium and magnesium compounds of 2-viny