55386-54-4Relevant academic research and scientific papers
Is 2,3,4,5-tetramethoxybenzoyl chloride a natural product?
Punch, Kathryn A.,Ghisalberti, Emilio L.,Piggott, Matthew J.
experimental part, p. 1348 - 1350 (2011/07/08)
The title compound, which was reported to be a constituent of the fruiting body of the fungus Antrodia camphorata, has been synthesized. The reactivity and spectroscopic properties of the synthetic material do not match those of the natural product. There
Chiral oxazoline route to enantiomerically pure biphenyls: Magnesio and copper mediated asymmetric hetero- and homo-coupling reactions
Meyers,Nelson, Todd D.,Moorlag, Henk,Rawson, David J.,Meier, Anton
, p. 4459 - 4473 (2007/10/03)
A series of chiral biphenyls were prepared via asymmetric reactions involving chiral oxazolines. One series of chiral biphenyls was reached by the magnesium mediated coupling of aryl bromides (via their Grignard reagents) with o-methoxyaryl oxazolines. In
A highly stereoselective synthesis of axially chiral biaryls. Application to the synthesis of a potential chiral catalyst
Meyers,Meier,Rawson
, p. 853 - 856 (2007/10/02)
Excellent diastereoselectivities (>98.2) have been obtained in the biaryl coupling of 2',6',-disubstituted aryl Grignard reagents 1 with aryl oxazolines 6, conveniently synthesised from the optically pure amino alcohols L-valinol and (S)-t-leucinol.
