55456-46-7

Basic information

• Product Name: 1-Pyrrolidinecarboxaldehyde, 2-(hydroxymethyl)-, (S)-
• CAS NO: 55456-46-7
• Molecular Formula: C6H11NO2
• Molecular Weight: 129.159
• Mol File: 55456-46-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-Pyrrolidinecarboxaldehyde, 2-(hydroxymethyl)-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Pyrrolidinecarboxaldehyde, 2-(hydroxymethyl)-, (S)-(55456-46-7)
• EPA Substance Registry System: 1-Pyrrolidinecarboxaldehyde, 2-(hydroxymethyl)-, (S)-(55456-46-7)

Safety Data

• Hazardous Substances Data: 55456-46-7(Hazardous Substances Data)

Upstream product

• 75-87-6 chloral 
• 23356-96-9 (S)-1-Pyrrolidin-2-yl-methanol 
• 50-00-0 formaldehyd 
• 107-31-3 Methyl formate 
• 64-18-6 formic acid 
• 147-85-3 L-proline 
• 50978-45-5 3-oxobenzo[d]isothiazole-2(3H)-carbaldehyde 1,1-dioxide 
• 109-94-4 formic acid ethyl ester 

Downstream Products

• 89597-95-5 (S)-(-)-2-(((2,4,6-trimethylbenzyl)oxy)methyl)-1-formyl-pyrrolidine 
• 95312-82-6 (S)-(-)-1-carbamoyl-2-methoxymethylpyrrolidine 
• 59983-39-0 (S)-1-amino-2-(methoxymethyl)pyrrolidine 
• 143008-27-9 (E)-2-((S)-2-Methoxymethoxymethyl-pyrrolidin-1-ylmethyl)-1,3-diphenyl-propenone 
• 63126-47-6 (2S)-2-(methoxymethyl)-1-pyrrolidine 
• 89597-97-7 (2S)-benzyloxymethyl-pyrrolidine 
• 34381-71-0 (S)-2-hydroxymethyl-1-methylpyrrolidine 
• 89597-96-6 (S)-(-)-1-Formyl-2-(((triphenylmethyl)oxy)methyl)-pyrrolidine 
• 63126-45-4 (S)-2-(methoxymethyl)pyrrolidine-1-carbaldehyde 

Relevant articles and documents

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The initial [2 + 2]-cycloadduct between a chromium aminocarbene and a tethered alkene undergoes a β-hydrogen elimination very efficiently when triphenylphosphine is added as a ligand. The reaction gives cyclic enamines or homoenamines depending on the sub

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Synthesis of C2-symmetrical bis-β-amino alcohols and their application in the enantioselective addition of diethylzinc to aldehydes

The C2-symmetrical bis-β-amino alcohols 1-6 were prepared and especially attention is focused on bridges, which link the two β-amino alcohol units. These ligands have been applied as chiral catalysts in the asymmetric addition of diethylzinc to aldehydes. sec-Alcohols have been obtained in good yields with up to 95.4% enantiomeric excess.