55527-82-7Relevant articles and documents
Product of ditoluenetitanium(0) oxidation with oxygen as a new catalyst for ethylene polymerization
Kvashina,Efimov,Chapysheva,Roshchupkina
, p. 2115 - 2117 (2007)
The reaction of ditoluenetitanium(0) with oxygen affords an intermediate oxidation product: a titanium(II) complex that catalyzes ethylene polymerization.
Modeling macroscale metal vapor reactions: Synthesis of bis(η6-naphthalene)titanium
Morand, Pascale D.,Francis, Colin G.
, p. 56 - 61 (2008/10/08)
The interaction of metal vapors of Cr, V, and Ti with naphthalene, and selected naphthalene derivatives, has been studied by means of matrix-isolation UV-visible spectroscopy. The electronic spectra of the Cr and V products are analyzed in terms of their known bis(η6-arene)metal conformations via a simple molecular orbital ordering scheme. On the basis of the data for Cr and V, the spectra of the Ti species appear to be best assigned to an analogous bis(η6-naphthalene)titanium complex. Preliminary studies on the reactivity of this complex reveal that it is apparently thermally stable at 290 K under matrix conditions, although it exhibits high reactivity toward ether solvents even at 190 K.