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5629-57-2

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5629-57-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 5629-57-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,6,2 and 9 respectively; the second part has 2 digits, 5 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 5629-57:
(6*5)+(5*6)+(4*2)+(3*9)+(2*5)+(1*7)=112
112 % 10 = 2
So 5629-57-2 is a valid CAS Registry Number.

5629-57-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name ethyl 4-phenyl-3-butenoate

1.2 Other means of identification

Product number -
Other names 4-Phenyl-but-3-ensaeure-aethylester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:5629-57-2 SDS

5629-57-2Relevant articles and documents

Generation of reactive species by one-electron reduction of Fischer-type carbene complexes of group 6 metals and their use for carbon - Carbon bond formation

Fuchibe, Kohei,Iwasawa, Nobuharu

, p. 905 - 914 (2003)

Carbon - carbon bond-forming reactions mediated by one-electron reduction of Fischer-type carbene complexes of Group 6 metals were investigated. In the case of aryl- or silylcarbene complexes of tungsten, the anion radical species generated by one-electro

Cobalt(i)-catalysed CH-alkylation of terminal olefins, and beyond

Giedyk, Maciej,Goliszewska, Katarzyna,ó Proinsias, Keith,Gryko, Dorota

supporting information, p. 1389 - 1392 (2016/01/25)

Cobalester, a natural nontoxic vitamin B12 derivative, was found to catalyse unusual olefinic sp2 C-H alkylation with diazo reagents as a carbene source instead of the expected cyclopropanation.

Ring Expansion of Epoxides under Br?nsted Base Catalysis: Formal [3+2] Cycloaddition of β,γ-Epoxy Esters with Imines Providing 2,4,5-Trisubstituted 1,3-Oxazolidines

Kondoh, Azusa,Odaira, Kenta,Terada, Masahiro

, p. 11240 - 11244 (2016/07/06)

A novel ring-expansion reaction of epoxides under Br?nsted base catalysis was developed. The formal [3+2] cycloaddition reaction of β,γ-epoxy esters with imines proceeds in the presence of triazabicyclodecene (TBD) as a superior Br?nsted base catalyst to afford 2,4,5-trisubstituted 1,3-oxazolidines in a highly diastereoselective manner. This reaction involves the ring opening of the epoxides with the aid of the Br?nsted base catalyst to generate α,β-unsaturated esters having an alkoxide at the allylic position, which would formally serve as a synthetic equivalent of the 1,3-dipole, followed by a cycloaddition reaction with imines in a stepwise fashion. This methodology enables the facile synthesis of enantioenriched 1,3-oxazolidines from easily accessible enantioenriched epoxides.

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