5654-72-8

Basic information

• Product Name: Thiocyanic acid, 2-phenylethyl ester
• CAS NO: 5654-72-8
• Molecular Formula: C9H9NS
• Molecular Weight: 163.243
• Mol File: 5654-72-8.mol
• Article Data: 30

Chemical Properties

• CAS DataBase Reference: Thiocyanic acid, 2-phenylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Thiocyanic acid, 2-phenylethyl ester(5654-72-8)
• EPA Substance Registry System: Thiocyanic acid, 2-phenylethyl ester(5654-72-8)

Safety Data

• Hazardous Substances Data: 5654-72-8(Hazardous Substances Data)

Upstream product

• 333-20-0 potassium thioacyanate 
• 622-24-2 2-phenylethyl chloride 
• 114050-31-6 3-Phenyl-propionic acid 2-thioxo-2H-pyridin-1-yl ester 
• 1424-52-8 p-tolylsulfonyl isothiocyanate 
• 14629-58-4 trimethyl(phenethyloxy)silane 
• 1147550-11-5 ammonium thiocyanate 
• 4410-99-5 2-mercaptophenylethane 
• 859214-49-6 2-cyano-4-chloro-5-methoxypyridazin-3(2H)-one 
• 60-12-8 2-phenylethanol 
• 540-72-7 sodium thiocyanide 
• 103-63-9 1-phenyl-2-bromoethane 
• 7677-24-9 trimethylsilyl cyanide 
• 49838-80-4 2,2'-sulfinylbis(ethane-2,1-diyl)dibenzene 
• 34372-24-2 1-benzylthio-2-phenylethane 

Downstream Products

• 4025-71-2 2-phenylethylsulfonyl chloride 
• 109942-79-2 5-(phenethylsulfanyl)-1H-tetrazole 
• 64768-46-3 S-phenethyl 2-phenylethane-1-sulfonothioate 
• 4410-99-5 2-mercaptophenylethane 
• 27846-22-6 diphenethyl disulfide 
• 361182-15-2 {2-[(trifluoromethyl)thio]ethyl}benzene 

Relevant articles and documents

An ionic liquid supported on magnetite nanoparticles as an efficient heterogeneous catalyst for the synthesis of alkyl thiocyanates in water

The present study describes a convenient method to synthesize alkyl thiocyanates from alkyl halides with the use of a novel nanomagnetic-supported organocatalyst (MNP@PEG-ImCl). The new supported ionic liquid is fully characterized by field-emission scanning electron microscopy (FESEM), Fourier-transform infrared (FT-IR), energy dispersive X-ray analysis (EDAX), X-ray powder diffraction (XRD), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM) as well as thermogravimetric analysis (TGA) techniques. It is noteworthy that we observed easy separation of the catalyst from the reaction mixture by a simple magnetic decantation and its reutilization many times without any appreciable loss of activities.

Sulfuryl Fluoride Promoted Thiocyanation of Alcohols: A Practical Method for Preparing Thiocyanates

A novel SO 2F 2-promoted thiocyanation method for the one-step synthesis of thiocyanates through C-O bond cleavage of readily available alcohols with ammonium thiocyanate as the thiocyanating agent was developed. The method avoids the use of additional catalyst, and a variety of (hetero)arene, alkene and aliphatic alcohols reacted with high efficiency in ethyl acetate under mild conditions to afford the corresponding thiocyanates in excellent to quantitative yields with broad functional-group compatibility.

Eosin-Mediated Alkylsulfonyl Cyanation of Olefins

Eosin-Y (EY)-mediated alkylsulfonyl cyanation of olefins was shown to afford alkylsulfonyl nitriles in good yields. On the basis of transient absorption spectroscopy, the reaction was shown to proceed via photoinduced electron transfer from 3EY? to an O-cyanated derivative of the photocatalyst, formed in situ, with generation of the corresponding sulfinate that is oxidized by EY?.+ into a sulfonyl radical. Addition of the latter on the olefin, followed by a radical cyano group transfer, then furnished the nitrile along with a RSO2 radical sustaining the radical chain.