57314-28-0

Upstream product

• 801-06-9 2,4,6-triphenyl-4H-pyran 
• 448-61-3 2,4,6-triphenylpyrylium tetrafluoroborate 
• 7647-01-0 hydrogenchloride 
• 896106-09-5 (Z)-1,3,5-Triphenyl-pent-2-en-4-yn-1-ol 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 23809-15-6 2,4,6-triphenylpyranyl 
• 67-63-0 isopropyl alcohol 
• 1484-88-4 2,4,6-triphenylpyrilium perchlorate 
• 100-52-7 benzaldehyde 
• 98-86-2 acetophenone 
• 103-82-2 phenylacetic acid 
• 1817-49-8 1,3-diphenyl-1-propyn-3-ol 
• 94055-32-0 2,4-dibromo-1,3,5-triphenyl-pentane-1,5-dione 
• 94055-33-1 1,3,5-triphenyl-2-bromo-1,5-pentanedione 

Downstream Products

• 5369-55-1 2,4-diphenylfuran 
• 576169-89-6 3,5-diphenyl-furan-2-carboxylic acid 
• 924645-22-7 3,5-diphenylfuran-2-carbonitrile 

Relevant academic research and scientific papers

Gold(I)-Catalyzed and H2O-Mediated Carbene Cascade Reaction of Propargyl Diazoacetates: Furan Synthesis and Mechanistic Insights

A novel gold-catalyzed water-mediated carbene cascade reaction of propargyl diazoacetates has been developed. Mechanistic investigation indicates that this reaction is initiated by gold-catalyzed gold-carbene formation followed by an unprecedented 6-endo-

An eco-benign and high speed protocol for the synthesis of 2-aroyl-3,5-diarylfuran derivatives using Teflon-supported iodine

Abstract: A new, practical, and convenient approach has been established for the expeditious synthesis of bioactive 2-aroyl-3,5-diarylfurans in excellent yields using a iodine-impregnated Teflon by a microwave-promoted process. The products are isolated w

Synthesis of 2-aroylfuran and novel 3,5-diaroyl-4-arylisoxazole derivatives by ring contraction of pyrylium salts

Ring contraction of 2,4,6-triarylpyrylium perchlorates by use of sodium nitrite mediated by ionic liquid has been used as a new, direct, and environmentally benign method for synthesis of bioactive 2-aroylfuran and novel 3,5-diaroyl-4-arylisoxazole deriva

An innovative and atom-efficient synthesis of bioactive 2-aroylfuran derivatives using macroporous polymer-supported cyanide

A novel and safe approach was developed for the synthesis of bioactive 2-aroyl-3,5-diarylfurans in excellent yields by using a cyanide-impregnated anion-exchange resin as a versatile reagent. The possibility of reusing the polymer-supported reagent makes the process environmentally friendly and economically advantageous. Georg Thieme Verlag Stuttgart. New York.

Free radicals: XXVIII. Reaction of 2,4,6-triphenylpyranyl with (diacetoxy-λ3-iodanyl)benzene

The major product of the reaction of 2,4,6-triphenylpyranyl with (diacetoxy-λ3-iodanyl)benzene in acetonitrile and acetone was 2,4,6-triphenylpyrylium acetate. Analogous reaction in isopropyl alcohol resulted in the formation of methane, carbon dioxide, 1,3,5-triphenylpent-2-ene- 1,5-dione, 2-benzoyl-3,5-diphenylfuran, 1,3,5-triphenylpenta-2,4-dien-1-one, and a small amount of 2,4,6-triphenylpyrilium acetate.

New synthetic approach for the construction of multisubstituted 2-acyl furans by the IBX-mediated cascade oxidation/cyclization of cis-2-En-4-yn-1-ols (IBX = 2-iodoxybenzoic acid)

A new approach for the construction of multisubstituted 2-acyl furans through cis-2-En-4-yn-1-ols (IBX=2-iodoxybenzoic acid)-mediated oxidation/cyclization in dimethyl sulfoxidse (DMSO) was developed. The results show that the introduction of an alkyl group at Cl provided a satisfactory yield of furan of 60% at 90°C. It is seen that IBX act as an electrophile to promote the cycloaddition of carbonyl group to the alkyne moiety. The furan derivatives are found to be useful synthetic intermediates for access to the compounds bearing biological activity. The studies also elucidate this reaction mechanism and extend the scope of synthetic utility of multisubstituted 2-acyl furans.

A convenient regioselective synthesis of 2,4-diarylfurans

A facile three step process, under mild conditions, for the synthesis of 2,4-diarylfurans with the same or different substituents on the two aryl rings, starting from benzaldehydes and acetophenones, employing Haller-Bauer type cleavage of 2-aroyl-3,5-diarylfurans is described.

The reaction of 1,3,5-triaryl-2-pentene-1,5-diones with bromine

Bromination of 1,3,5-triaryl-2-pentene-1,5-diones results in the formation of a mixture of aryl-substituted 4-bromo-2-pentene-1,5-diones. In the presence of sodium acetate, this reaction affords 4-acetoxy-2-pentene-1,5-diones and products of intramolecula

Oxidation reactions of 4H-chalcogenopyrans

We have studied the oxidation of 4H-chalcogenopyrans and chalcogenopyrylium salts by lead tetraacetate. We have established that the major reaction products on oxidation of 2,6-diphenyl-4H-thiopyran and selenopyran are 2,6-diphenyl-4H-thio(seleno)pyran-4-

Oxidation of 4H-Pyran, 4H-Thiopyran, and 4H-Selenopyran with Lead Tetraacetate

Oxidation of 2,4,6-triphenyl-4H-pyran, 2,4,6-triphenyl-4H-thiopyran, and 2,4,6-triphenyl-4H-selenopyran with lead tetraacetate yields, respectively, 2-benzoyl-3,5-diphenylfuran, 2-benzoyl-3,5-diphenylthiophene, and 2-benzoyl-3,5-diphenylselenophene.