582-92-3

Basic information

• Product Name: bis(4-fluorophenyl)peroxyanhydride
• Synonyms: Bis(4-fluorophenyl)peroxyanhydride
• CAS NO: 582-92-3
• Molecular Formula: C₁₄H₈F₂O₄
• Molecular Weight: 278.2077
• Mol File: 582-92-3.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 371.7°C at 760 mmHg
• Flash Point: 172.5°C
• Density: 1.38g/cm³
• Vapor Pressure: 1.01E-05mmHg at 25°C
• Refractive Index: 1.555
• CAS DataBase Reference: bis(4-fluorophenyl)peroxyanhydride(CAS DataBase Reference)
• NIST Chemistry Reference: bis(4-fluorophenyl)peroxyanhydride(582-92-3)
• EPA Substance Registry System: bis(4-fluorophenyl)peroxyanhydride(582-92-3)

Safety Data

• Hazardous Substances Data: 582-92-3(Hazardous Substances Data)

Upstream product

• 352-32-9 p-fluorotoluene 
• 456-22-4 4-Fluorobenzoic acid 
• 403-43-0 4-fluorobenzoyl chloride 

Downstream Products

• 113490-25-8 4-Fluorbenzoyloxyl-Radikal 
• 49834-29-9 N-(tert-butyl)-4-fluorobenzamide 
• 1057224-07-3 3-(4-fluorophenyl)-1-methylquinoxalin-2(1H)-one 
• 99504-73-1 2-(4-fluorophenyl)-5-phenyl-2H-tetrazole 
• 462-06-6 fluorobenzene 
• 75-46-7 trifluoromethan 
• 459-47-2 1-ethyl-4-fluorobenzene 
• 456-22-4 4-Fluorobenzoic acid 
• 398-23-2 4,4'-difluorobiphenyl 
• 352-32-9 p-fluorotoluene 
• 1266355-98-9 3-(1-octen)-yl 4-fluorobenzoate 
• 324-74-3 4-fluoro-biphenyl 
• 632335-04-7 6-(4′-fluorophenyl)phenanthridine 

Relevant articles and documents

Aryl acyl peroxides for visible-light induced decarboxylative arylation of quinoxalin-2(1: H)-ones under additive-, metal catalyst-, and external photosensitizer-free and ambient conditions

Aryl radicals were generated for the first time from cheap and easily available aryl acyl peroxides in eco-friendly ethyl acetate under ambient conditions and visible-light illumination in the absence of any additive, metal catalyst, or external photosensitizer. The present arylation of quinoxalin-2(1H)-ones was chemo- and regioselective, and provided good access to various 3-arylquinoxalin-2(1H)-ones. This journal is

Uncatalyzed, on water oxygenative cleavage of inert C-N bond with concomitant 8,7-amino shift in 8-aminoquinoline derivatives

Oxygenative cleavage of an inert CAr-NH2 bond with concomitant 1,2 amine migration in 8-aminoquinoline derivatives is reported in water at room temperature. The reaction is highly atom- and step-economical as both C- and N-containing fragments of the C-N bond cleavage are incorporated into the target molecule and is effected without the need for N-oxide. The reaction is scalable to gram level, and the products are useful as electrophilic partners for coupling reactions, ligands in catalysis and bioactive compounds.

A highly efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides

An efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides was developed. A variety of anilides reacted with aryl acylperoxides to afford the corresponding ortho-arylation products, and N-methoxyarylamides generated phenanthridinones. This journal is