5827-17-8Relevant articles and documents
A twin-sulfur [...]/aryl heterocyclic compound phosphoric acid as the auxiliary ligand iridium complex of (by machine translation)
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Paragraph 0033; 0034; 0038, (2018/09/21)
The invention relates to a nitrogen heterocyclic main ligand, in order to double-sulfur [...]/aryl heterocyclic phosphate compound as auxiliary ligand new iridium complex. Iridium complex molecular nitrogen heterocyclic and sulfur group contribute to improving the material of the electron mobility and control light-emitting color, so as to balance the cavity with electronic injection and transmission, widen the carrier composite area, promote the device efficiency, reduce efficiency roll-off. The invention the iridium complex synthetic simple, stable chemical property, easy to sublimation purification, device performance, in order to obtain high efficiency of the organic electroluminescent device and its application in the field of lighting and display provides the convenience. (by machine translation)
ZUR KENNTNIS DES NATRIUMDIPHENYLPHOSPHINOFORMIATS Ph2PCOONa
Diemert, Klaus,Hahn, Thomas,Kuchen, Wilhelm
, p. 287 - 294 (2007/10/02)
Ph2PCOONa 2, prepared from Ph2PNa and CO2, is readily hydrolyzed in protic media with formation of Ph2PH and CO2.Hydrolysis is much slower in NaOH and small quantities of Ph2P(O)O- and HCOO- are additionally formed.Reactions of 2 with RI in stoichiometrical amounts gave tertiary phosphines Ph2PR (R=Me, Et) while the phosphonium compound I resulted from 2 and MeI in excess.Ph2PCOOMe, Ph2PCOOSiMe3 or Ph2PCSSNa were obtained from 2 and (MeO)2SO2, Me3SiCl or CS2.Ph2P(O)ONa and Ph2P(S)SNa were isolated when 2 was reacted with O2 or S8 in benzene.