59176-57-7

Upstream product

• 62762-44-1 lithium bis(trimethylsilyl)(phenylthio)methylide 
• 100-52-7 benzaldehyde 
• 17873-08-4 (phenylsulfanylmethyl)trimethylsilane 
• 100-68-5 methyl-phenyl-thioether 
• 37891-39-7 trimethylsilane 
• 87729-86-0 Bis(phenylthio)bis(trimethylsilyl)methane 
• 130083-74-8 (1-Methoxy-2-phenyl-1-phenylsulfanyl-ethyl)-trimethyl-silane 
• 76200-41-4 trimethyl(2-phenyl-1-(phenylthio)ethyl)silane 
• 75-77-4 chloro-trimethyl-silane 
• 34917-41-4 2-phenylethyl phenyl sulfoxide 
• 62761-90-4 α,α-bis(trimethylsilyl)methylphenyl sulfide 

Downstream Products

• 128881-80-1 8-methoxy-3-phenyl-2-phenylsulfonyl-1-tetralone 
• 2170-06-1 1-Phenyl-2-(trimethylsilyl)acetylene 
• 74632-92-1 (1,3-Bis-benzenesulfonyl-2-phenyl-pentyl)-trimethyl-silane 
• 74632-90-9 (1-Benzenesulfonyl-2-phenyl-hexyl)-trimethyl-silane 
• 74632-91-0 (1-Benzenesulfonyl-3-methyl-2-phenyl-pentyl)-trimethyl-silane 
• 343621-05-6 (1-Benzenesulfonyl-2-phenyl-propyl)-trimethyl-silane 
• 70738-48-6 phenyl 2-phenylpropyl sulfone 
• 74632-95-4 ((Z)-1-Benzenesulfonyl-2-phenyl-vinyl)-trimethyl-silane 
• 74632-96-5 (1-benzenesulfonyl-2-phenylvinyl)trimethylsilane 
• 128881-73-2 2-phenyl-1-phenylsulfonyl-1-(trimethylsilyl)ethene 
• 37167-62-7 bromo-phenyl-acetic acid methyl ester 

Relevant academic research and scientific papers

A highly stereoselective synthesis of (z)-1-phenylthio-1-trialkyl- silylalkenes from 1-methoxy-1-phenylthio-1 - trialkylsilylalkanes

A new method for the highly stereoselective synthesis of (Z) -1-phenylthio-1-trialkylsilylalkenes 3 by the elimination of methanol from 1-methoxy-1-phenylthio-1-trialkylsilylalkane 2 in organic solvents is described.

A Facile Stereoselective Synthesis of α-Silyl Substituted Vinyl Sulfides

A facile one-pot synthesis of α-silyl substituted vinyl sulfides which involves the chlorination of 1-phenylthio-1-silylalkanes followed by dehydrochlorination is described.

ELIMINATIVE DEOXYGENATION: THE FACILE FORMATION OF α-TRIMETHYLSILYL VINYL SULFIDES FROM SULFOXIDES

Synthetically useful α-trimethylsilyl vinyl sulfides are generated in high yields by deoxygenation of the corresponding sulfoxides in the presence of excess LDA and trimethylsilyl chloride.

HETEROCONJUGATE ADDITION OF LITHIUM ALKYLS TO SUBSTITUTED HETERO-OLEFINS CONJUGATED WITH SULFUR AND SILICON ATOMS

Lithium alkyls and a lithiated sulfone carbanion readily added to the substituted hetero-olefins conjugated with silicon and sulfone-sulfur atoms among other combination of the third (or fourth) row hetero atoms, e.g.Si, Se and S.