59325-16-5Relevant academic research and scientific papers
BMIm HCO3: an ionic liquid with carboxylating properties. Synthesis of carbamate esters from amines
Di Nicola,Arcadi,Rossi
supporting information, p. 9895 - 9898 (2016/12/07)
1-Butyl-3-methylimidazolium hydrogen carbonate (BMIm HCO3) was used as an ionic liquid with carboxylating properties able to convert, in the presence of an alkyl halide, amines into the corresponding carbamate esters. Moderate to good yields of
ORGANIC COMPOUNDS
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Page 9-10, (2010/02/09)
Tertiary non-vinylic carbamates of molecular weight less than 350 are useful as fragrance ingredients. A method of preparation is also described.
REACTION DES CHLOROFORMIATES SUR LES AMINES TERTIAIRES: COMPETITION ENTRE N-DEMETHYLATION, DESAMINATION, N-DEBENZYLATION ET N-DESALLYLATION
Kapnang, Henriette,Charles, Georges
, p. 3233 - 3236 (2007/10/02)
In ten cases investigated for the title reaction, N-debenzylation and N-deallylation are favoured over deamination and N-demethylation.
HYDROGENATION OF N-ARYL CARBAMATES TO N-ALICYCLIC CARBAMATES.
Malz Jr.,Greenfield
, p. 358 - 362 (2007/10/06)
An economical, high-yield process is developed for the preparation of pure N-alicyclic carbamates by the rhodium-catalyzed hydrogenation of the corresponding N-aryl carbamates. The N-aryl carbamates are obtained by the simple reaction of low-cost aromatic
