59550-02-6Relevant articles and documents
Double- and triple-consecutive O-insertion into tert-butyl and triarylmethyl structures
Krasutsky, Pavel A.,Kolomitsyn, Igor V.,Krasutsky, Sergiy G.,Kiprof, Paul
, p. 2539 - 2542 (2007/10/03)
(Matrix Presented) The concecutive Criegee rearrangement reactions were studied for tert-butyl trifluoroacetate, triarylcarbinols, and benzophenone ketales with trifluoroperacetic acid (TFPAA) in trifluoroacetic acid (TFA). The formation of methyl acetate and methyl trifluoroacetate indicates that the consecutive double-O-insertion process has taken place for tert-butyl trifluoroacetate. The intermediate dimethoxymethylcarbonium ion was detected below 5°C. A consecutive triple-O-insertion process has been observed for triarylmethanols and benzophenone ketals. A new high yield method of corresponding diaryl carbonates synthesis was developed.