596-31-6Relevant articles and documents
Photoactivatable aggregation-induced emission of triphenylmethanol
Zheng, Yue,Zheng, Xiaokun,Xiang, Yu,Tong, Aijun
, p. 11130 - 11133 (2017)
Triphenylmethanol (TPOH) is a non-fluorescent compound. Interestingly, after UV irradiation at 254 nm, TPOH showed a strong blue fluorescence on a solid surface. Moreover, the fluorescence can be quenched by UV irradiation at 365 nm, making the photoactiv
On the Mechanism of the Cleavage Reaction of (Methylthio)methyl Ether with Triphenylmethyl Cation
Niwa, Haruki,Miyachi, Yasuyoshi
, p. 716 - 718 (1991)
The cleavage reaction of a (methylthio)methyl (MTM) ether with triphenylmethyl cation was not initiated by the previously proposed hydride abstraction with triphenylmethyl cation but promoted by the coordination of triphenylmethyl cation as a Lewis acid to the sulfur atom in the MTM group.
Selective reaction of benzyl alcohols with HI gas: Iodination, reduction, and indane ring formations
Matsumoto, Shoji,Naito, Masafumi,Oseki, Takehisa,Akazome, Motohiro,Otani, Yasuhiko
, p. 7254 - 7259 (2017/11/24)
Reactions of benzyl alcohols with HI in solvent-free conditions were examined. Three types of reactions (iodination, reduction, and ring formation) occurred depending on the degree of crowding around the benzyl position and the benzylic stabilization of substrates. Results also showed that the ring formation to give indanes proceeded efficiently when HI was used, and that compounds with electron-rich aromatic rings gave indane derivatives in good yields.