968-39-8

Basic information

• Product Name: ETHYLTRITYLETHER
• Synonyms: ETHYLTRITYLETHER;(Trityloxy)ethane;ETHYL TRIPHENYLMETHYL ETHER;[ethoxy(diphenyl)methyl]benzene
• CAS NO: 968-39-8
• Molecular Formula: C₂₁H₂₀O
• Molecular Weight: 288.3829
• Mol File: 968-39-8.mol
• Article Data: 15

Chemical Properties

• Boiling Point: 382.1°Cat760mmHg
• Flash Point: 202.1°C
• Appearance: /
• Density: 1.059g/cm³
• CAS DataBase Reference: ETHYLTRITYLETHER(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYLTRITYLETHER(968-39-8)
• EPA Substance Registry System: ETHYLTRITYLETHER(968-39-8)

Safety Data

• Hazardous Substances Data: 968-39-8(Hazardous Substances Data)

Usage

Uses

(Ethoxydiphenylmethyl)benzene is an analog of Clotrimazole (CLT), a synthetic anti-fungal imidazole derivative that inhibits tumor cell proliferation and angiogenesis.

Synthesis Reference(s)

Tetrahedron Letters, 22, p. 2107, 1981 DOI: 10.1016/S0040-4039(01)93289-7

Upstream product

• 64-17-5 ethanol 
• 153010-95-8 1-methoxy-5-trityloxy-3-oxapentane 
• 76-83-5 trityl chloride 
• 17714-76-0 trityl p-toluate 
• 17714-77-1 trityl benzoate 
• 596-31-6 methoxytriphenylmethane 
• 595-91-5 triphenylacetic acid 
• 3736-70-7 triphenylphosphonyl dichloride 
• 596-43-0 bromo-triphenyl-methane 
• 2303-76-6 sodium diethyl phosphite 
• 76-84-6 triphenylmethyl alcohol 
• 119-61-9 benzophenone 
• 16735-19-6 2-amino-1-phenylpropan-1-one hydrochloride 
• 5736-21-0 sodium triphenylmethoxyde 

Downstream Products

• 34914-36-8 2-(triphenylmethylthio)ethanoic acid 
• 29167-19-9 tritylmercapto-acetic acid ethyl ester 
• 64-17-5 ethanol 
• 94440-27-4 dicyclohexyl-phenyl-methane 
• 24523-63-5 S-trityl-3-thiopropanol 
• 5427-11-2 4-methylphenyl triphenylmethyl sulfide 
• 107766-79-0 triphenylcarbonium tetrachloroethoxy(isopropylimido)tungsten(VI) 
• 113337-74-9 (3aR,4S,7R,7aS)-3-Hydroxy-2-[4-(hydroxy-diphenyl-methyl)-phenyl]-3a,4,7,7a-tetrahydro-4,7-methano-inden-1-one 
• 113337-79-4 (3aS,4R,7S,7aR)-2-(4-Benzhydrylidene-cyclohexa-2,5-dienylidene)-3a,4,7,7a-tetrahydro-4,7-methano-indene-1,3-dione 
• 113337-80-7 2-(4-Benzhydrylidene-cyclohexa-2,5-dienylidene)-phenalene-1,3-dione 
• 113337-77-2 2-(4-Benzhydrylidene-cyclohexa-2,5-dienylidene)-indan-1,3-dione 
• 113337-76-1 2-(4-Benzhydrylidene-cyclohexa-2,5-dienylidene)-cyclopent-4-ene-1,3-dione 
• 26234-46-8 2-phenyl-3a,4,7,7a-tetrahydro-1H-4,7-methanoisoindole-1,3(2H)-dione 
• 10072-02-3 2-ethoxy-1,3,2-benzodioxaphosphole 

Relevant articles and documents

A Self-Assembled Cage with Endohedral Acid Groups both Catalyzes Substitution Reactions and Controls Their Molecularity

A self-assembled Fe4L6 cage complex internally decorated with acid functions is capable of accelerating the thioetherification of activated alcohols, ethers and amines by up to 1000-fold. No product inhibition is seen, and effective

New reaction of organic monohalides with orthoformates

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Tetrazoles: XLIV. Synthesis and chemical properties of 5-substituted 2-triphenylmethyltetrazoles

Tritylation of tetrazole and its 5-substituted derivatives with triphenylmethyl chloride under conditions of phase-transfer catalysis regioselectively yields the corresponding 5-substituted 2-trityltetrazoles which can be used to protect N-H bonds in nitrogen-containing heterocycles and O-H bonds in primary alcohols. Thermolysis of 2-trityltetrazoles in benzonitrile leads to 3,6-disubstituted 1,2,4,5-tetrazines. Thermal transformation of the same compounds in dodecane follows a radically different mechanism, resulting in formation of difficultly accessible 8,8-diphenylheptafulvenes. The structure of the latter was proved by X-ray analysis.