59700-95-7

Upstream product

• 96-48-0 4-butanolide 
• 4440-01-1 lithium phenylacetylide 
• 1394313-89-3 6-phenylhex-5-yne-1,4-diol 
• 59700-84-4 4-oxo-6-phenyl-5-hexynoic acid methyl ester 
• 140844-83-3 (4S)-hydroxy-6-phenyl-5-hexynoic acid methyl ester 
• 140844-83-3 4-hydroxy-6-phenyl-5-hexynoic acid methyl ester 
• 6738-06-3 phenylethynylmagnesium bromide 

Downstream Products

• 18138-77-7 (E)-2-styryltetrahydrofuran 
• 125225-54-9 (4R,5R)-5-hydroxy-6-phenyl-4-hexanolide 
• 140844-93-5 3-((4R,5R)-5-Benzyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-propionaldehyde 
• 151692-01-2 3-((4R,5R)-5-Benzyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-propionic acid 
• 140844-89-9 (3R)-6-t-butyldimethylsilyloxy-1,2-epoxy-1-phenylhexane-3-ol 
• 140844-90-2 [3-((R)-5-Benzyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-propoxy]-tert-butyl-dimethyl-silane 
• 140844-91-3 (4R,5R)-3-(2,2-dimethyl-5-phenylmethyl-1,3-dioxolan-4-yl)propan-1-ol 
• 140844-88-8 (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (R)-4-(tert-butyl-dimethyl-silanyloxy)-1-((E)-styryl)-butyl ester 
• 140844-88-8 (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-4-(tert-butyl-dimethyl-silanyloxy)-1-((E)-styryl)-butyl ester 
• 140844-86-6 (E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-1-phenyl-hex-1-en-3-ol 
• 140844-87-7 (R,Z)-6-t-butyldimethylsilyloxy-1-phenyl-1-hexen-3-ol 

Relevant academic research and scientific papers

Boronic acid catalysis as a mild and versatile strategy for direct carbo- and heterocyclizations of free allylic alcohols

BAC to the future: Boronic acid catalysis (BAC) was applied to the direct activation of alcohols leading to the preparation of carbocycles (see scheme), benzofurans, tetrahydrofurans, pyrrolidines, pyrans, piperidines, and various polycyclic compounds. The reactions proceed under mild conditions that circumvent the use of reactive leaving groups like halides. Copyright

Enantioselective carbanion cyclization of 5-alkenyl carbamates induced by asymmetric lithiation with s-butyllithium/(-)-sparteine system

Treatment of (E)-6-phenyl-5-hexenyl carbamates with s-BuLi/(-)-sparteine is shown to afford the trans-1,2-disubstituted cyclopentane derivatives in high % ee, along with the bicyclo[3.1.0]hexanes (bicyclization products).

Synthesis of the (4R,5R)-Isomer of 5-Hydroxy-6-phenyl-4-hexanolide, a Lateral Root-inducing Substance Isolated from Erwinia quercina

Lipase-catalyzed enantioselective lactonization of racemic methyl 6-phenyl-4-hydroxy-5-hexynoate worked well to afford (R)-6-phenyl-5-hexyn-4-olide (42 percent yield, 81 percent e.e.).The e.e. of the product was enhanced to 97 percent by the repetition of