59700-84-4

Upstream product

• 13146-23-1 copper(I) phenylacetylenide 
• 1490-25-1 succinic acid monomethylester chloride 
• 6738-06-3 phenylethynylmagnesium bromide 
• 3878-55-5 methyl hydrogen succinate 
• 67-56-1 methanol 
• 14901-29-2 4-oxo-6-phenylhex-5-ynoic acid 
• 536-74-3 phenylacetylene 

Downstream Products

• 140844-88-8 (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (S)-4-(tert-butyl-dimethyl-silanyloxy)-1-((E)-styryl)-butyl ester 
• 140844-88-8 (R)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (R)-4-(tert-butyl-dimethyl-silanyloxy)-1-((E)-styryl)-butyl ester 
• 140924-18-1 (4R,5S)-3-(2,2-dimethyl-5-phenylmethyl-1,3-dioxolan-4-yl)propan-1-ol 
• 140844-91-3 (4R,5R)-3-(2,2-dimethyl-5-phenylmethyl-1,3-dioxolan-4-yl)propan-1-ol 
• 140844-87-7 (R,Z)-6-t-butyldimethylsilyloxy-1-phenyl-1-hexen-3-ol 
• 140844-86-6 (E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-1-phenyl-hex-1-en-3-ol 
• 140844-85-5 (-)-(S)-γ-(2-phenylethynyl)-γ-butyrolactone 
• 140844-84-4 (-)-(R)-γ-(2-phenylethynyl)-γ-butyrolactone 
• 59700-95-7 (E)-(S)-6-Phenyl-hex-5-ene-1,4-diol 
• 59700-95-7 (E)-(R)-6-Phenyl-hex-5-ene-1,4-diol 
• 140844-90-2 [3-((R)-5-Benzyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-propoxy]-tert-butyl-dimethyl-silane 
• 140844-89-9 (3R)-6-t-butyldimethylsilyloxy-1,2-epoxy-1-phenylhexane-3-ol 
• 151692-01-2 3-((4R,5R)-5-Benzyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-propionic acid 
• 140844-93-5 3-((4R,5R)-5-Benzyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-propionaldehyde 

Relevant academic research and scientific papers

Catalytic Ynone-Amidine Formal [4 + 2]-Cycloaddition for the Regioselective Synthesis of Tricyclic Azepines

A Ca(OTf)2- and self-promoted ynone-amidine atom-economic formal [4 + 2]-cycloaddition of various ynones with amidines is reported for the construction of highly functionalized tricyclic azepines. High reaction rate, ease of operation, and high product se

Asymmetric transfer hydrogenation of functionalized acetylenic ketones

A systematic study of the asymmetric transfer hydrogenations of functionalized acetylenic ketones and diketones has been completed, together with a total synthesis of (S,S)-(-)-yashabushidiol B. In several cases, excellent enantioselectivities and yields

Synthesis of the (4R,5R)-Isomer of 5-Hydroxy-6-phenyl-4-hexanolide, a Lateral Root-inducing Substance Isolated from Erwinia quercina

Lipase-catalyzed enantioselective lactonization of racemic methyl 6-phenyl-4-hydroxy-5-hexynoate worked well to afford (R)-6-phenyl-5-hexyn-4-olide (42 percent yield, 81 percent e.e.).The e.e. of the product was enhanced to 97 percent by the repetition of