60211-89-4Relevant academic research and scientific papers
vic-Iodothiocyanates and Iodoisothiocyanates. Part 8. Addition of Iodine-Thiocyanogen to Alkenes under Ionic and Radical Conditions
Cambie, Richard C.,Rutledge, Peter S.,Strange, Gary A.,Woodgate, Paul D.
, p. 553 - 565 (2007/10/02)
Addition of iodine-thiocyanogen to alkenes in the dark proceeds by a regioselective ionic reaction to give mainly vic-iodoisothiocyanates, and under irradiation with u.v. light by a radical reaction to give mainly vic-iodothiocyanates.However, in the case of 1-methylene-4-t-butylcyclohexane even under irradiation by u.v. light, ionic addition of the reagent competes successfully with, and almost to the exclusion of, the radical pathway.
REACTION OF OLEFINS WITH A MIXTURE OF IODINE AND MERCURY(II) THIOCYANATE. PREDOMINANT FORMATION OF vic-IODO(ISOTHIOCYANATO)ALKANES.
Watanabe,Uemura,Okano
, p. 2458 - 2462 (2007/10/02)
Treatment of olefins with a mixture of iodine and mercury(II) thiocyanate in benzene or diethyl ether gives vic-iodo(isothiocyanato)alkanes and vic-iodo(thiocyanato)alkanes in a high yield, the former being predominant. Similar results were obtained by us
vic-Iodothiocyanates and Iodoisothiocyanates. Part 4. The Synthesis of 2-Substituted-2-thiazolines
Cambie, Richard C.,Chambers, David,Rutledge, Peter S.,Woodgate, Paul D.
, p. 40 - 51 (2007/10/02)
The reactions of trans-1-iodo-2-isothiocyanatocyclohexane with a number of carbon nucleophiles to form 2-substituted-2-thiazolines are described.Reactions of several vic-iodoisothiocyanates with butil-lithium give products which are dependent on the solvent and/or temperature.
vic-Iodothiocyanates and Iodoisothiocyanates. Part 3. Further Preperations, and the Formation of 2-Alkoxy-2-thiazolines
Cambie, Richard C.,Chambers, David,Rutledge, Peter S.,Woodgate, Paul D.,Woodgate, Shella D.
, p. 33 - 39 (2007/10/02)
The reactions of (E)-hex-3-ene, 4-t-butylcyclohexene, and 3-t-butylcyclohexene with iodine and potassium thiocyanate are examined.The action of iodine and thiocyanogen with (E)-hex-3-ene gives different results from those reported in the literature.Isomerization of the vic-iodothiocyatates and formation of 2-alkoxy-2-thiazolines from the latter adducts are reported.
