604-95-5

Basic information

• Product Name: 2-nitrophenanthrene-9,10-dione
• Synonyms: 2-Nitrophenanthrene-9,10-dione; 9,10-Phenanthrenedione, 2-nitro-
• CAS NO: 604-95-5
• Molecular Formula: C₁₄H₇NO₄
• Molecular Weight: 253.2097
• Mol File: 604-95-5.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 474.3°C at 760 mmHg
• Flash Point: 244.9°C
• Density: 1.481g/cm³
• Vapor Pressure: 3.66E-09mmHg at 25°C
• Refractive Index: 1.688
• CAS DataBase Reference: 2-nitrophenanthrene-9,10-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 2-nitrophenanthrene-9,10-dione(604-95-5)
• EPA Substance Registry System: 2-nitrophenanthrene-9,10-dione(604-95-5)

Safety Data

• Hazardous Substances Data: 604-95-5(Hazardous Substances Data)

Upstream product

• 17024-18-9 2-nitrophenanthrene 
• 7697-37-2 nitric acid 
• 84-11-7 9,10-phenanthrenequinone 
• 40138-16-7 2-formylbenzene boronic acid 
• 84459-32-5 2-bromo-5-nitrobenzaldehyde 
• 1392143-84-8 4-nitro-[1,1'-biphenyl]-2,2'-dicarbaldehyde 
• 85-01-8 phenanthrene 
• 64-19-7 acetic acid 

Downstream Products

• 7647-01-0 hydrogenchloride 
• 36043-49-9 2-aminophenanthrene-9,10-dione 
• 91693-19-5 6-Brom-2-nitro-fluoren-9-on 
• 5101-11-1 2-Nitro-9,10-bis-(N-benzyloxycarbonyl-glycyloxy)-phenanthren 
• 4088-81-7 2-hydroxy-phenanthrene-9,10-dione 
• 7463-77-6 2-nitro-phenanthrene-9,10-dione-(Z,Z)-dioxime 
• 7463-76-5 2-nitro-phenanthrene-9,10-dione dioxime 

Relevant articles and documents

Suzuki cross coupling followed by cross dehydrogenative coupling: An efficient one pot synthesis of Phenanthrenequinones and analogues

An efficient one pot protocol has been developed towards the synthesis of substituted phenanthrenequinone and analogous derivatives via Suzuki cross coupling followed by copper catalyzed cross dehydrogenative coupling.

The first colorimetric receptor for the B4O72- anion based on nitro substituted phenanthroimidazole ferrocene derivatives

Four phenanthroimidazole ferrocene derivatives (2a-2d) were designed, synthesized and characterized by 1H NMR, 13C NMR and high-resolution mass spectroscopy (HRMS). Recognition of 12 anions by 2a-2d was investigated by UV-Vis absorption analysis, showing that 2b and 2d sensed B4O72- selectively among the tested anions with an obvious color change observed. 1H NMR titrations and theoretical calculations demonstrated that 2b binds B4O72- through O?H hydrogen bonding and O?B interactions between the nitro moiety and the B4O72- anion.

Process for the production of nitro derivatives of aromatic compounds

Nitroderivates of aromatic compounds which are difficult to nitrate, can readily be obtained by nitration providing that the aromatic compound is treated with nitric acid or another nitrating agent in the presence of aliphatic or cycloaliphatic hydrocarbons monosubstituted or polysubstituted by halogen, the nitro group or an alkyl sulphonyl group, and the nitro derivative formed subsequently isolated.