60483-07-0Relevant articles and documents
Metal-free C(sp3)–H oxidation of 2-methylquinolines with PIDA under microwave irradiation
Jiang, Long,Huang, Yingyi,Yan, Yiyan,Xie, Yuanyuan
supporting information, p. 4149 - 4151 (2016/08/24)
An efficient metal-free protocol has been developed for the sp3C–H bond oxidation of 2-methylquinolines in the presence of PIDA under microwave irradiation, providing 2-quinolinecarboxaldehydes with moderate to high yields and excellent selectivities. A wide range of 2-quinolinecarboxaldehydes with different functional groups have been synthesized. A tentative mechanism has been presented to explain this highly selective oxidation process.