605-05-0

Basic information

• Product Name: (9-Phenanthryl)phenylmethane
• Synonyms: (9-Phenanthryl)phenylmethane;9-Benzylphenanthrene
• CAS NO: 605-05-0
• Molecular Formula: C₂₁H₁₆
• Molecular Weight: 268.35174
• Mol File: 605-05-0.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 452°Cat760mmHg
• Flash Point: 221.2°C
• Appearance: /
• Density: 1.131g/cm³
• Vapor Pressure: 6.2E-08mmHg at 25°C
• Refractive Index: 1.696
• CAS DataBase Reference: (9-Phenanthryl)phenylmethane(CAS DataBase Reference)
• NIST Chemistry Reference: (9-Phenanthryl)phenylmethane(605-05-0)
• EPA Substance Registry System: (9-Phenanthryl)phenylmethane(605-05-0)

Safety Data

• Hazardous Substances Data: 605-05-0(Hazardous Substances Data)

Usage

General Description

(9-Phenanthryl)phenylmethane is a chemical compound with the molecular formula C20H16. It is also known as 9-phenylphenanthrene due to its structure, which consists of a phenanthrene ring with a phenyl group attached at the 9-position. (9-Phenanthryl)phenylmethane is often used as a building block in the synthesis of various organic compounds, particularly in the field of organic chemistry. It can also be used as a fluorescent probe in biological and medicinal research due to its unique structural and electronic properties. Additionally, (9-Phenanthryl)phenylmethane has potential applications in materials science, particularly in the development of organic electronics and optoelectronic devices. Overall, this chemical compound has important implications in various scientific and technological fields due to its versatile properties and potential applications.

InChI:InChI=1/C21H16/c1-2-8-16(9-3-1)14-18-15-17-10-4-5-11-19(17)21-13-7-6-12-20(18)21/h1-13,15H,14H2

Upstream product

• 27094-39-9 (9-benzyl-fluoren-9-yl)-methanol 
• 3274-87-1 toluene-4-sulfonic acid-(9-benzyl-fluoren-9-ylmethyl ester) 
• 85-01-8 phenanthrene 
• 100-44-7 benzyl chloride 
• 71112-64-6 9-phenanthrylmagnesium bromide 
• 854220-76-1 2-[9]phenanthryl-1,1,1,2-tetraphenyl-ethane 
• 7732-18-5 water 
• 7553-56-2 iodine 
• 64-19-7 acetic acid 
• 4707-72-6 9-hydroxymethylphenanthrene 
• 100-59-4 phenylmagnesium chloride 
• 3262-89-3 triphenylboroxine 
• 68572-87-2 9-phenanthrenylboronic acid 
• 100-39-0 benzyl bromide 

Downstream Products

• 84-11-7 9,10-phenanthrenequinone 
• 65-85-0 benzoic acid 
• 60084-42-6 9-Benzyl-9,10-dihydrophenanthren 

Relevant articles and documents

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Pd(II)-NHDC-Functionalized UiO-67 Type MOF for Catalyzing Heck Cross-Coupling and Intermolecular Benzyne-Benzyne-Alkene Insertion Reactions

A novel palladium N-heterocyclic bis-carbene dicarboxylate ligand (Pd-NHDC-H2L) was successfully synthesized. In addition, an Pd-NHDC-containing UiO-67 type MOF (UiO-67-Pd-NHDC) was prepared on the basis of a size-matched ligand mixture of biphenyl-4,4′-dicarboxylic acid/Pd-NHDC-H2L (9/1) and ZrCl4 under solvothermal conditions. The obtained UiO-67-Pd-NHC MOF can be a highly heterogeneous catalyst to promote Heck cross-coupling and intermolecular benzyne-benzyne-alkene insertion reactions.

Cross-Coupling of Phenol Derivatives with Umpolung Aldehydes Catalyzed by Nickel

A nickel-catalyzed cross-coupling to construct the C(sp2)-C(sp3) bond was developed from two sustainable biomass-based feedstocks: phenol derivatives with umpolung aldehydes. This strategy features the in situ generation of moisture/air-stable hydrazones from naturally abundant aldehydes, which act as alkyl nucleophiles under catalysis to couple with readily available phenol derivatives. The avoidance of using both halides as the electrophiles and organometallic or organoboron reagents (also derived from halides) as the nucleophiles makes this method more sustainable. Water tolerance, great functional group (ketone, ester, free amine, amide, etc.) compatibility, and late-stage elaboration of complex biological molecules exemplified its practicability and unique chemoselectivity over organometallic reagents.