6069-98-3

Basic information

• Product Name: CIS-1-ISOPROPYL-4-METHYLCYCLOHEXANE
• Synonyms: 1-Isopropyl-4-methyl-cyclohexane, cis;1-Isopropyl-cis-4-methylcyclohexane;1-Methyl-4-(1-methylethyl)-cyclohexane, cis;1-Methyl-cis-4-isopropylcyclohexane;cis-1-methyl-4-(1-methylethyl)cyclohexane;cis-1-methyl-4-(1-methylethyl)-cyclohexane;cis-cyclohexan;cis-p-Menthane
• CAS NO: 6069-98-3
• Molecular Formula: C₁₀H₂₀
• Molecular Weight: 140.27
• Mol File: 6069-98-3.mol
• Article Data: 76

Chemical Properties

• Melting Point: -89.9°C
• Boiling Point: 167°C
• Flash Point: 38°C
• Appearance: /
• Density: 0,81 g/cm3
• Refractive Index: 1.4431
• CAS DataBase Reference: CIS-1-ISOPROPYL-4-METHYLCYCLOHEXANE(CAS DataBase Reference)
• NIST Chemistry Reference: CIS-1-ISOPROPYL-4-METHYLCYCLOHEXANE(6069-98-3)
• EPA Substance Registry System: CIS-1-ISOPROPYL-4-METHYLCYCLOHEXANE(6069-98-3)

Safety Data

• Statements: 10
• Safety Statements: 16
• RIDADR: 3295
• Hazardous Substances Data: 6069-98-3(Hazardous Substances Data)

Usage

General Description

CIS-1-ISOPROPYL-4-METHYLCYCLOHEXANE is a chemical compound with the molecular formula C10H20. It is a cycloalkane, specifically a methylcyclohexane derivative, with a branched isopropyl group attached to the first carbon atom. CIS-1-ISOPROPYL-4-METHYLCYCLOHEXANE is used in various industrial applications, such as in the production of fragrances, flavorings, and other organic chemicals. It is also used as a solvent and as a precursor for the synthesis of other organic compounds. CIS-1-ISOPROPYL-4-METHYLCYCLOHEXANE has a variety of potential uses in the chemical and manufacturing industries due to its unique chemical properties and structure.

Upstream product

• 61585-35-1 p-menth-1-ene 
• 1879-04-5 8-bromo-p-menthane 
• 586-62-9 Terpinolene 
• 1197-01-9 p-cymene-8-ol 
• 99-87-6 4-methylisopropylbenzene 
• 5989-27-5 D-limonene 
• 554-59-6 carane 
• 2451-01-6 cis-4-hydroxy-α,α,4-trimethyl-cyclohexanemethanol, monohydrate 
• 89-48-5 2-isopropyl-5-methylcyclohexyl acetate 
• 3626-19-5 cis epoxyde du carvomenthene 
• 3626-19-5 trans epoxyde du carvomenthene 
• 138-86-3 limonene. 
• 60-29-7 diethyl ether 
• 89-82-7 pulegone 

Downstream Products

• 3239-03-0 (Z)-p-menthan-4-ol 
• 3901-93-7 (Z)-4-isopropyl-1-methylcyclohexan-1-ol 
• 3901-95-9 cis p-menthanol 
• 491-07-6 isomenthone 
• 491-07-6 (+/-)-menthone 
• 499-70-7 methyl-2 isopropyl-5 cyclohexanone 
• 499-70-7 methyl-2 isopropyl-5 cyclohexanone 
• 99-82-1 cation radical of cis-4-methylisopropylcyclohexane 
• 99-87-6 4-methylisopropylbenzene 
• 1195-32-0 1-methyl-4-isopropenylbenzene 
• 498-81-7 p-menthan-8-ol 
• 4331-54-8 4-methylcyclohexanecarboxylic acid 
• 62067-45-2 4-isopropyl cyclohexane carboxylic acid 
• 3728-56-1 1-ethyl-4-methyl-cyclohexane 

Relevant articles and documents

Continuous synthesis of menthol from citronellal and citral over Ni-beta-zeolite-sepiolite composite catalyst

One-pot continuous synthesis of menthols both from citronellal and citral was investigated over 5 wt% Ni supported on H-Beta-38-sepiolite composite catalyst at 60–70 °C under 10–29 bar hydrogen pressure. A relatively high menthols yield of 53% and 49% and stereoselectivity to menthol of 71–76% and 72–74% were obtained from citronellal and citral respectively at the contact time 4.2 min, 70 °C and 20 bar. Citral conversion noticeably decreased with time-on-stream under 10 and 15 bar of hydrogen pressure accompanied by accumulation of citronellal, the primary hydrogenation product of citral, practically not affecting selectivity to menthol. A substantial amount of defuctionalization products observed during citral conversion, especially at the beginning of the reaction (ca. 1 h), indicated that all intermediates could contribute to formation of menthanes. Ni/H-Beta-38-sepiolite composite material prepared by extrusion was characterized by TEM, SEM, XPS, XRD, ICP-OES, N2 physisorption and FTIR techniques to perceive the interrelation between the physico-chemical and catalytic properties.

RhNPs supported onN-functionalized mesoporous silica: effect on catalyst stabilization and catalytic activity

Amine and nicotinamide groups grafted on ordered mesoporous silica (OMS) were investigated as stabilizers for RhNPs used as catalysts in the hydrogenation of several substrates, including carbonyl and aryl groups. Supported RhNPs on functionalized OMS were prepared by controlled decomposition of an organometallic precursor of rhodium under dihydrogen pressure. The resulting materials were characterized thoroughly by spectroscopic and physical techniques (FTIR, TGA, BET, SEM, TEM, EDX, XPS) to confirm the formation of spherical rhodium nanoparticles with a narrow size distribution supported on the silica surface. The use of nicotinamide functionalized OMS as a support afforded small RhNPs (2.3 ± 0.3 nm), and their size and shape were maintained after the catalyzed acetophenone hydrogenation. In contrast, amine-functionalized OMS formed RhNP aggregates after the catalytic reaction. The supported RhNPs could selectively reduce alkenyl, carbonyl, aryl and heteroaryl groups and were active in the reductive amination of phenol and morpholine, using a low concentration of the precious metal (0.07-0.18 mol%).

STRONGLY LEWIS ACIDIC METAL-ORGANIC FRAMEWORKS FOR CONTINUOUS FLOW CATALYSIS

Lewis acidic metal-organic framework (MOF) materials comprising triflate-coordinated metal nodes are described. The materials can be used as heterogenous catalysts in a wide range of organic group transformations, including Diels-Alder reactions, epoxide-ring opening reactions, Friedel-Crafts acylation reactions and alkene hydroalkoxylation reactions. The MOFs can also be prepared with metallated organic bridging ligands to provide heterogenous catalysts for tandem reactions and/or prepared as composites with support particles for use in columns of continuous flow reactor systems. Methods of preparing and using the MOF materials and their composites are also described.