60779-18-2

Upstream product

• 100-66-3 methoxybenzene 
• 108-59-8 malonic acid dimethyl ester 
• 27798-60-3 methyl 2-(2-methoxyphenyl)acetate 
• 616-38-6 carbonic acid dimethyl ester 
• 93-25-4 2-methoxyphenylacetic acid 

Downstream Products

• 20730-59-0 2-(2-methoxyphenyl)-1,3-propanediol 
• 1401354-95-7 C₂₅H₂₉NO₄ 
• 1401354-82-2 α-tert-butoxycarbonyl-α-(2-methoxyphenyl)-γ-methylidene-δ-valerolactone 
• 219708-70-0 [(E)-3-(2-Methoxy-phenyl)-4-(2-oxo-4-phenylsulfanyl-oxazolidin-3-yl)-but-1-enyl]-phosphonic acid diethyl ester 
• 219708-61-9 3-[3-(tert-Butyl-dimethyl-silanyloxy)-2-(2-methoxy-phenyl)-propyl]-4-phenylsulfanyl-oxazolidin-2-one 
• 219708-57-3 3-[3-(tert-Butyl-dimethyl-silanyloxy)-2-(2-methoxy-phenyl)-propyl]-4-hydroxy-oxazolidin-2-one 
• 219708-67-5 2-(2-Methoxy-phenyl)-3-(2-oxo-4-phenylsulfanyl-oxazolidin-3-yl)-propionaldehyde 
• 219708-64-2 3-[3-Hydroxy-2-(2-methoxy-phenyl)-propyl]-4-phenylsulfanyl-oxazolidin-2-one 
• 219708-53-9 3-[3-(tert-Butyl-dimethyl-silanyloxy)-2-(2-methoxy-phenyl)-propyl]-oxazolidine-2,4-dione 
• 219708-51-7 3-(tert-Butyl-dimethyl-silanyloxy)-2-(2-methoxy-phenyl)-propan-1-ol 

Relevant academic research and scientific papers

DIMETHYL ARYLMALONATES FROM CERIUM(IV) AMMONIUM NITRATE PROMOTED REACTIONS OF DIMETHYL MALONATE WITH AROMATIC COMPOUNDS IN METHANOL

Aromatic compounds undergo homolytic malonylation by reaction with cerium(IV) ammonium nitrate and dimethyl malonate in methanol at room temperature.

Palladium-catalyzed asymmetric synthesis of 2-pyrrolidinones with a quaternary carbon stereocenter

A palladium-catalyzed asymmetric synthesis of 2-pyrrolidinones with a quaternary stereocenter at the 3-position has been achieved by the reaction of γ-methylidene-δ-valerolactones with alkyl isocyanates. High enantioselectivity has been realized by employing a newly synthesized chiral phosphoramidite ligand. The Royal Society of Chemistry 2012.