61548-33-2

Basic information

• Product Name: (isooctadecanoato-O)bis(methacrylato-O)(propan-2-olato)titanium
• Synonyms: Isopropyl dimethacryloyl isostearoyl titanate; Isopropyl dimethacryl isostearoyl titanate; (Isooctadecanoato-O)bis(methacrylato-O)(propan-2-olato)titanium; Titanium, (isooctadecanoato-kappaO)bis(2-methyl-2-propenoato-kappaO)(2-propanolato)-; 16-methylheptadecanoic acid; 2-methylprop-2-enoic acid; propan-2-ol; titanium
• CAS NO: 61548-33-2
• Molecular Formula: C₄H₆O
• Molecular Weight: 564.6177
• EINECS: 262-836-4
• Mol File: 61548-33-2.mol
• Article Data: 37

Chemical Properties

• Boiling Point: 400.8°C at 760 mmHg
• Flash Point: 225.6°C
• Vapor Pressure: 1.52E-07mmHg at 25°C
• CAS DataBase Reference: (isooctadecanoato-O)bis(methacrylato-O)(propan-2-olato)titanium(CAS DataBase Reference)
• NIST Chemistry Reference: (isooctadecanoato-O)bis(methacrylato-O)(propan-2-olato)titanium(61548-33-2)
• EPA Substance Registry System: (isooctadecanoato-O)bis(methacrylato-O)(propan-2-olato)titanium(61548-33-2)

Safety Data

• Hazardous Substances Data: 61548-33-2(Hazardous Substances Data)

Usage

General Description

Titanium bis(methacrylato-O)(propan-2-olato) is a chemical compound with the molecular formula C28H50O8Ti. It is an organometallic complex containing a central titanium atom bonded to two methacrylate groups, an isooctadecanoate group, and a propan-2-olato group. (isooctadecanoato-O)bis(methacrylato-O)(propan-2-olato)titanium is commonly used as a catalyst or co-catalyst in various polymerization reactions, particularly in the production of acrylic and methacrylic polymers. It is also utilized as a crosslinking agent and as a component in adhesives and coatings. Additionally, titanium bis(methacrylato-O)(propan-2-olato) has potential applications in photovoltaic devices and other electronic devices.

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Relevant articles and documents

Heteropoly blue as a reaction-controlled phase-transfer catalyst for the epoxidation of olefins

A new reaction-controlled phase-transfer catalyst system has been designed and synthesized. In this system, heteropoly blue, [C7H 7N(CH3)3]3PMo4O 16, is used for the catalytic epoxidation of olefins with H 2O2 as the oxidant. In this system, the catalyst not only can be recovered, like heterogeneous catalyst, but also acts as a homogeneous catalyst. The main products are epoxide of olefins and H2O; no co-product forms. The system exhibits high conversion and selectivity as well as excellent catalyst stability. 31PNMR spectra, UV-vis spectra, and infrared spectra are used to analyze the reason for the phase transfer of the catalyst, indicating that the change of structure leads to the formation of reaction-controlled phase-transfer catalyst.

Ultraselective epoxidation of butadiene on Cu{111} and the effects of Cs promotion [6]

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Enantioselective Radical-Polar Crossover Reactions of Indanonecarboxamides with Alkenes

Highly efficient asymmetric intermolecular radical-polar crossover reactions were realized by combining a chiral N,N′-dioxide/NiII complex catalyst with Ag2O under mild reaction conditions. Various terminal alkenes and indanonecarboxamides/esters underwent radical addition/cyclization reactions to afford spiro-iminolactones and spirolactones with good to excellent yields (up to 99 %) and enantioselectivities (up to 97 % ee). Furthermore, a range of different radical-mediated oxidation/elimination or epoxide ring-opening products were obtained under mild reaction conditions. The Lewis acid catalysts exhibited excellent performance and precluded the strong background reaction.

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