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61949-23-3

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61949-23-3 Usage

General Description

L-menthyl formate is a chemical compound that belongs to the class of organic compounds known as formates. It is a clear, colorless liquid with a minty odor and is commonly used as a flavoring agent and fragrance ingredient. L-menthyl formate is found naturally in various plants and is also produced synthetically for commercial use. It is often used in cosmetics, personal care products, and food products to impart a fresh, minty scent. In addition to its aromatic properties, L-menthyl formate also has potential applications as a pesticide and insect repellent due to its natural repellent properties towards certain pests. It is important to note that L-menthyl formate should be handled with care as it can cause irritation to the skin and eyes.

Check Digit Verification of cas no

The CAS Registry Mumber 61949-23-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,1,9,4 and 9 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 61949-23:
(7*6)+(6*1)+(5*9)+(4*4)+(3*9)+(2*2)+(1*3)=143
143 % 10 = 3
So 61949-23-3 is a valid CAS Registry Number.
InChI:InChI=1/C11H20O2/c1-8(2)10-5-4-9(3)6-11(10)13-7-12/h7-11H,4-6H2,1-3H3/t9-,10+,11-/m1/s1

61949-23-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name (-)-menthyl formate

1.2 Other means of identification

Product number -
Other names L-MENTHYL FORMATE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:61949-23-3 SDS

61949-23-3Relevant articles and documents

Photo-on-Demand Synthesis of Vilsmeier Reagents with Chloroform and Their Applications to One-Pot Organic Syntheses

Liang, Fengying,Eda, Kazuo,Okazoe, Takashi,Wada, Akihiro,Mori, Nobuaki,Konishi, Katsuhiko,Tsuda, Akihiko

, p. 6504 - 6517 (2021/05/06)

The Vilsmeier reagent (VR), first reported a century ago, is a versatile reagent in a variety of organic reactions. It is used extensively in formylation reactions. However, the synthesis of VR generally requires highly toxic and corrosive reagents such as POCl3, SOCl2, or COCl2. In this study, we found that VR is readily obtained from a CHCl3 solution containing N,N-dimethylformamide or N,N-dimethylacetamide upon photo-irradiation under O2 bubbling. The corresponding Vilsmeier reagents were obtained in high yields with the generation of gaseous HCl and CO2 as byproducts to allow their isolations as crystalline solid products amenable to analysis by X-ray crystallography. With the advantage of using CHCl3, which bifunctionally serves as a reactant and a solvent, this photo-on-demand VR synthesis is available for one-pot syntheses of aldehydes, acid chlorides, formates, ketones, esters, and amides.

N-Heterocyclic Carbene Catalyzed Transformylation

Fernando, Jared E. M.,Levens, Alison,Moock, Daniel,Lupton, David W.

, p. 3505 - 3510 (2017/07/27)

The N-heterocyclic carbene (NHC) catalyzed transformylation has been developed for the conversion of 1°, 2°, and 3° alcohols to the corresponding formates. The reaction employs low catalyst loadings and methyl formate as the formyl transfer reagent. The scope of the reaction is broad with 23 examples reported with good yields (59-96%). The reaction is insensitive to common nitrogen and oxygen protecting groups and can be achieved in the presence of a number of heterocycles.

Preparation of alkyl formates from corresponding alcohols using ethyl formate catalyzed by poly(4-vinylpyridinium tribromide) under neutral and solvent-free conditions

Ghorbani-Choghamarani, Arash,Norouzi, Masoomeh

experimental part, p. 1399 - 1402 (2011/12/15)

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