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Usage

Uses

Used in Plasticizer Industry:
Dicyclohexyl oxalate is used as a plasticizer for the production of specific polymers, such as cellulose acetate butyrate and other resins. It enhances the flexibility and workability of these materials, making them more suitable for various applications.
Used in Polymer Cross-linking:
In the polymer industry, dicyclohexyl oxalate serves as a cross-linking agent, facilitating the formation of chemical bonds between polymer chains. This improves the mechanical properties and stability of the resulting polymers.
Used in Chemical Processes as a Solvent:
Dicyclohexyl oxalate is utilized as a solvent in a variety of chemical processes, where its ability to dissolve other substances aids in the efficiency and effectiveness of these processes.
Used in Organic Synthesis:
It has been studied for its potential use in organic synthesis, where it may act as a reagent or intermediate in the production of other organic compounds.
Used in Photo-polymerization as a Photoinitiator:
Dicyclohexyl oxalate is also considered for use as a photoinitiator in photo-polymerization reactions, where it can initiate the polymerization process upon exposure to light, leading to the formation of polymers with specific properties.
Safety Note:
While dicyclohexyl oxalate offers a range of applications, it is important to handle it with care due to its potential to cause skin and eye irritation. Additionally, it may be harmful if ingested or inhaled, necessitating proper safety measures during its use.

InChI:InChI=1/C14H22O4/c15-13(17-11-7-3-1-4-8-11)14(16)18-12-9-5-2-6-10-12/h11-12H,1-10H2

Upstream product

• 144-62-7 oxalic acid 
• 108-93-0 cyclohexanol 
• 253-52-1 PHTHALAZINE 
• 35448-12-5 2-(cyclohexyloxy)-2-oxoacetic acid 
• 491-35-0 C₆H₄NCH₂CHCCH₂ 
• 2459-09-8 4-pyridinecarboxylic acid, methyl ester 
• 79-37-8 oxalyl dichloride 

Downstream Products

• 110-83-8 cyclohexene 

Relevant academic research and scientific papers

Copper-catalyzed asymmetric methylation of fluoroalkylated pyruvates with dimethylzinc

The catalytic asymmetric methylation of fluoroalkylated pyruvates is shown with dimethylzinc as a methylating reagent in the presence of a copper catalyst bearing a chiral phosphine ligand. This is the first catalytic asymmetric methylation to synthesize various α-fluoroalkylated tertiary alcohols with CF3, CF2H, CF2Br, and n-CnF2n+1 (n = 2, 3, 8) groups in good-to-high yields and enantioselectivities. Axial backbones and substituents on phosphorus atoms of chiral phosphine ligands critically influence the enantioselectivity. Moreover, the methylation of simple perfluoroalkylated ketones is found to be facilitated by only chiral phosphines without copper.

Radical Decarboxylative Alkylation onto Heteroaromatic Bases with Trivalent Iodine Compounds

Heteroaromatic bases containing nitrogen atoms were easily alkylated with carboxylic acids in the presence of benzene and pentafluorobenzene via radical pathways.Similarly, the alkylation onto heteroaromatic bases was carried out with oxalic acid monoalkyl esters, which were prepared from alcohols and oxalyl dichloride, in the presence of the same trivalent iodine compounds.Moreover, this system was applied to the synthesis of C-nucleosides with the carboxylic acids bearing a sugar moiety.

Alkylation of Aromatic Heterocycles with Oxalic Acid Monoalkyl Esters in the Presence of Trivalent Iodine Compounds

Aromatic heterocycles containing nitrogen atoms were easily alkylated with the half esters of oxalic acid, which were prepared from alcohols, in the presence of benzene via radical decarboxylative pathways.This is the first method for the alkylation of aromatic heterocycles with alcohols via the formation of half esters of oxalic acid.