62024-31-1Relevant articles and documents
Alkaloids of some Asian Sedum species
Kim Jeong-Hee,Hart,Stevens
, p. 1319 - 1324 (1996)
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Mechanistic studies on diamine oxidase: oxidation of α,ω-diamines does not involve an enamine intermediate
Gavin, Stephen S.,Equi, Angela M.,Robins, David J.
, p. 31 - 34 (2007/10/02)
Three β,β,β',β'-2H4-labelled α,ω-diamines were synthesized and incubated with pea seedling diamine oxidase.The aminoaldehydes formed by oxidative deamination cyclized to the corresponding imines, which were trapped with benzoylacetic acid.In all three cases the acetophenone derivatives produced were shown by NMR and mass spectrometry to contain four deuterium atoms.The retention of all four deuterium atoms demonstrates that oxidative deamination of α,ω-diamines catalyzed by pea seedling diamine oxidase does not involve an enamine intermediate as previously suggested.
A NEW EFFICIENT SYNTHESIS OF β-AMINOKETONES VIA Δ4-ISOXAZOLINES.
Mancuso, Vincent,Hootele, Claude
, p. 5917 - 5918 (2007/10/02)
β-aminoketones are prepared in good yield by hydrogenolysis (Pd/C) of the N-O bond of Δ4-isoxazolines obtained by 1,3-dipolar cycloaddition of nitrones with alkynes.