62086-71-9

Basic information

• Product Name: Glycine, N-(4-methoxybenzoyl)-, methyl ester
• CAS NO: 62086-71-9
• Molecular Formula: C11H13NO4
• Molecular Weight: 223.229
• Mol File: 62086-71-9.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: Glycine, N-(4-methoxybenzoyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Glycine, N-(4-methoxybenzoyl)-, methyl ester(62086-71-9)
• EPA Substance Registry System: Glycine, N-(4-methoxybenzoyl)-, methyl ester(62086-71-9)

Safety Data

• Hazardous Substances Data: 62086-71-9(Hazardous Substances Data)

Upstream product

• 5680-79-5 glycine ethyl ester hydrochloride 
• 100-07-2 4-methoxy-benzoyl chloride 
• 100-09-4 4-methoxybenzoic acid 
• 616-34-2 methoxycarbonylmethylamine 
• 67-56-1 methanol 
• 150-13-0 4-amino-benzoic acid 
• 123-11-5 4-methoxy-benzaldehyde 
• 201230-82-2 carbon monoxide 
• 19501-58-7 4-methoxyphenylhydrazine hydrochloride 
• 28507-33-7 quinolin-8-yl-4-methoxybenzoate 
• 104-92-7 1-bromo-4-methoxy-benzene 

Downstream Products

• 67567-57-1 2-(p-methoxyphenyl)-5-methoxyoxazole 

Relevant articles and documents

Quinolin-8-yl Formate: A New Option for Small-Scale Carbonylation Reactions in Microwave Reactors

A convenient procedure for conducting small-scale carbonylations of aryl or benzyl halides in a microwave reactor by using quinolin-8-yl formate is described. The resulting 8-acyloxyquinolines were shown to be more reactive than phenyl esters in acyl-tran

Copper-Catalyzed Aerobic Oxidative [2 + 3] Cyclization/Aromatization Cascade Reaction: Atom-Economical Access to Tetrasubstituted 4,5-Biscarbonyl Imidazoles

An atom-economical method for accessing tetrasubstituted 4,5-biscarbonylimidazoles by reaction between glycine derivatives and 5-alkoxyoxazoles is reported. The method, which involves a copper-catalyzed aerobic oxidative [2 + 3] cyclization/aromatization

Catalytic, asymmetric, and stereodivergent synthesis of non-symmetric β,β-Diaryl-α-Amino Acids

We report a concise, enantio- and diastereoselective route to novel nonsymmetrically substituted N-protected β,β-diaryl-α-amino acids and esters, through the asymmetric hydrogenation of tetrasubstituted olefins, some of the most challenging examples in the field. Stereoselective generation of an E- or Z-enol tosylate, when combined with stereoretentive Suzuki-Miyaura cross-coupling and enantioselective hydrogenation catalyzed by (NBD)2RhBF4 and a Josiphos ligand, allows for full control over the two vicinal stereogenic centers. High yields and excellent enantioselectivities (up to 99% ee) were obtained for a variety of N-acetyl, N-methoxycarbonyl, and N-Boc β,β-diaryldehydroamino acids, containing a diverse and previously unreported series of heterocyclic and aryl substituted groups (24 examples) and allowing access to all four stereoisomers of these valuable building blocks.