62114-59-4Relevant academic research and scientific papers
Regioselective allylation and alkylation of electron-deficient alkenes with organogallium and organoindium reagents
Araki, Shuki,Horie, Tomoaki,Kato, Motoshi,Hirashita, Tsunehisa,Yamamura, Hatsuo,Kawai, Masao
, p. 2331 - 2334 (2007/10/03)
Triorganogallium and -indium reagents reacted with α,β-unsaturated nitrile and carbonyl compounds to give 1,4-addition products regioselectively. The reaction of allylgallium and allylindium sesquihalides with α,β-unsaturated carbonyl compounds proceeded
SYNTHESE RADICALAIRE D'ANALGESIQUES POTENTIELS: ARYL-4 PIPERIDINES SUBSTITUEES EN 2 ET BENZOMORPHANES
Stella, L.,Raynier, B.,Surzur, J. M.
, p. 2843 - 2854 (2007/10/02)
The synthesis of a series of 3-aryl 5-hexenyl amines and the cyclisations of the corresponding N-chloroamines are described.When the ring closure results from the amino radical addition to the ethylenic double bond, 2-chloromethyl 4-phenyl piperidines are obtained.These compounds lead by intramolecular Friedel-Crafts reaction to varied substituted 6,7-benzomorphanes.When the phenyl ring is substituted with a methoxyl group, the cyclisation proceeds via homolytic aromatic substitution and 4-allyl tetrahydroquinolines are formed.
