62135-66-4

Basic information

• Product Name: N-(6-methylpyridin-2-yl)benzamide
• Synonyms: benzamide, N-(6-methyl-2-pyridinyl)-; N-(6-methyl-2-pyridinyl)benzamide
• CAS NO: 62135-66-4
• Molecular Formula: C₁₃H₁₂N₂O
• Molecular Weight: 212.2472
• Mol File: 62135-66-4.mol
• Article Data: 20

Chemical Properties

• Boiling Point: 273.3°C at 760 mmHg
• Flash Point: 119.1°C
• Density: 1.193g/cm³
• Vapor Pressure: 0.00579mmHg at 25°C
• Refractive Index: 1.636
• CAS DataBase Reference: N-(6-methylpyridin-2-yl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(6-methylpyridin-2-yl)benzamide(62135-66-4)
• EPA Substance Registry System: N-(6-methylpyridin-2-yl)benzamide(62135-66-4)

Safety Data

• Hazardous Substances Data: 62135-66-4(Hazardous Substances Data)

Upstream product

• 1824-81-3 2-Amino-6-methylpyridine 
• 536-74-3 phenylacetylene 
• 100-41-4 ethylbenzene 
• 2136-55-2 5-methyl-2-phenylimidazo[1,2-a]pyridine 
• 70-11-1 α-bromoacetophenone 
• 134-81-6 benzil 
• 98-85-1 1-Phenylethanol 
• 98-86-2 acetophenone 
• 103-82-2 phenylacetic acid 
• 102-96-5 (2-nitroethenyl)benzene 
• 18368-63-3 6-chloro-2-picoline 
• 55-21-0 benzamide 
• 100-47-0 benzonitrile 
• 5315-25-3 2-bromo-6-methylpyridine 

Downstream Products

• 4931-29-7 5-methyl-2-phenyl-[1,2,4]triazolo[1,5-a]pyridine 
• 70644-47-2 2-(benzylamino)-6-methylpyridine 

Relevant articles and documents

Copper(I)-catalysed aerobic oxidative selective cleavage of C[sbnd]C bond with DMAP: Facile access to N-substituted benzamides

A base/DMAP system for efficient oxidative cleavage of C(CO)–C(alkyl) bond to generate N-substituted benzamides has been developed in the presence of copper(I) chloride. The usage of inexpensive copper catalyst, broad substrate scope, mild conditions make

Singlet oxygen mediated dual C-C and C-N bond cleavage in visible light

A tandem cleavage of carbon-carbon and carbon-nitrogen bonds in imidazo[1,2-a]pyridines and imidazo[1,2-a]quinolines is reported in the presence of eosin Y and visible light. The ring opening occurs under ambient conditions through singlet oxygen insertio

Copper Catalyzed Oxidative C-C Bond Cleavage of 1,2-Diketones: A Divergent Approach to 1,8-Naphthalimides, Biphenyl-2,2′-dicarboxamides, and N-Heterocyclic Amides

We report here a simple and efficient copper catalyzed oxidative C-C bond cleavage of stable aromatic cyclic-fused and acyclic 1,2-diketones to deliver amides and imides in high yields. This newly developed protocol provides an excellent tool to transform structurally different 1,2-diketones into different products under the same reaction conditions. The key synthetic features of this methodology are the formation of 1,8-naphthalimides and biphenyl-2,2′-dicarboxamide motifs in high yields. The fluorescent studies of 1,8-naphthalimide derivatives were also carried out in order to show the potential application of these scaffolds.