6214-04-6Relevant articles and documents
DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents
Jones, Caroline S.,Bull, Steven D.,Williams, Jonathan M. J.
, p. 8452 - 8456 (2016/09/28)
Air-stable N-sulfonyl and N-phosphonyl DBN hexafluorophosphate salts have been synthesised under mild conditions as sulfonylating and phosphonylating agents. These salts are highly efficient in the sulfonylation and phosphonylation of a range of N- and O-nucleophiles to generate sulfonamides, sulfonate esters, phosphoramidates and phosphonate esters in good yields.
Nucleophilic Substitution at the Tetracoordinated Phosphorus Atom. Reactivity of Amines towards Diphenyl Chlorophosphate in Acetonitrile
Solomoichenko,Sadovskii,Savelova,Piskunova,Popov
, p. 1434 - 1441 (2007/10/03)
Tertiary alkylamines, pyridines, and imidazoles catalyze the hydrolysis of diphenylchlorophosphate (acetonitrile, 25°C) by a nucleophilic mechanism with the rate-determining attack of an amine on the substrate. Primary and secondary alkyl and arylamines f
THE REACTIVITY OF MANGANESE DIETHYLAMIDE WITH PHOSPHATE TRIESTERS
Fester, V. D.,Vather, S. M.,Modro, T. A.
, p. 281 - 283 (2007/10/02)
Manganese bis-(diethylamide) reacts with phosphoric triesters with a selective displacement of single ester function by the diethylamide group.In the reaction of the manganese reagent with dialkyl phosphites products of both, mono- and disubstitution were observed.
