62155-27-5

Usage

Uses

Used in Chemical Synthesis:
ACETIC ACID AMINOOXO METHYL ESTER is used as a precursor for the synthesis of important chemicals, including agrochemicals, dyes, and fragrance ingredients, due to its ability to facilitate the creation of a diverse array of compounds.
Used in Pharmaceutical Production:
ACETIC ACID AMINOOXO METHYL ESTER is used as a chemical intermediate in the manufacture of pharmaceuticals, contributing to the development of various medications.
Used in Flavor and Fragrance Industry:
ACETIC ACID AMINOOXO METHYL ESTER is used as a starting material in the synthesis of flavorings and perfumes, enhancing the aromatic profiles of these products.
Used in Polymer and Plastics Industry:
ACETIC ACID AMINOOXO METHYL ESTER is used in the production of polymers and plastics, playing a crucial role in the formation of these materials.
Used in Solvent Applications:
ACETIC ACID AMINOOXO METHYL ESTER is used as a solvent across various industries, capitalizing on its solubility properties to dissolve and process other substances.

InChI:InChI=1/C3H5NO3/c1-7-3(6)2(4)5/h1H3,(H2,4,5)

Upstream product

• 553-90-2 Dimethyl oxalate 
• 6263-52-1 methyl bromonitroacetate 
• 82208-51-3 Chloronitroacetic acid methyl ester 
• 7664-41-7 ammonia 
• 6096-81-7 dimethyl iminodiacetate 
• 5680-79-5 glycine ethyl ester hydrochloride 
• 543-27-1 isobutyl chloroformate 
• 67-56-1 methanol 
• 5977-14-0 acetoacetamido 
• 148705-17-3 diisopropenyl oxalate 

Downstream Products

• 17640-15-2 methyl cyanoformate 
• 98022-35-6 dichloro-methoxy-acetic acid amide 
• 62154-05-6 [(1RS,2RS)-2-hydroxymethyl-2-(4-nitro-phenyl)-ethyl]-oxalamide 

Relevant academic research and scientific papers

A novel [2 + 3] cycloaddition reaction: Singlet oxygen mediated formation of 1,3-dipole from iminodiacetic acid dimethyl ester and its addition to maleimides

Sensitized photolysis of iminodiacetic acid methyl ester and maleimides follows a [2 + 3] cycloaddition pathway yielding pyrrolidine derivatives. This is similar to the photochemical reaction between C60 and amines. A series of pyrrolidine derivatives are prepared by the method including multipyrrolidines from bis- and tris-maleimide starting materials. The yields range from 13% to 85%. The reaction is highly stereoselective. All the isolated products have the 1,3-dimethoxycarbonyl groups in the cis configuration. Various sensitizers may be used with slightly different yields. A plausible mechanism is proposed that involves the singlet oxygen abstraction of two α hydrogen atoms from the iminodiacetate and formation of a 1,3-dipole with a structure similar to the classical thermally generated 1,3-dipole.

Copper-Catalysed (Diacetoxyiodo)benzene-Promoted Aerobic Esterification Reaction: Synthesis of Oxamates from Acetoacetamides

A copper-catalysed (diacetoxyiodo)benzene-promoted aerobic esterification reaction of acetoacetamides was developed for the synthesis of oxamates, which are useful precursors in synthetic organic chemistry. This practical and mild synthetic approach proceeded at 25 °C under open-air conditions and afforded methyl 2-oxo-2-(phenylamino)acetates in good to excellent yields combined with C?C σ-bond cleavage and formal oxidative C?H bond functionalization. A mechanism is proposed. (Figure presented.).

Novel syntheses of oxamides, oxamates and oxalates from diisopropenyl oxalate

Diisopropenyl oxalate, obtained by catalytic addition of oxalic acid to propyne, is a useful reagent for the access to a variety of α-dicarbonyl compounds such as oxamides, oxamates and oxalates, under very mild conditions.

DECOMPOSITION PRODUCTS OF HALONITROACETIC ACID DERIVATIVES

The halonitro group O2NCHX of chloro- and bromonitroacetic acid derivatives underwent reduction to H2NCO upon boiling.The same derivatives decomposed to oxalic acid upon long storage.Likely chemical transformation pathways are discussed. Keywords: chloro- and bromonitroacetic acids, reduction, oxalic acid, amides.

Antibacterially active amides

Carboxylic acid amides of formula (II): STR1 where R1 and R2 represent a variety of hydrocarbon or heterocyclic groups, possess antibacterial activity and antimycoplasmal activity and are therefore of value in the treatment of human and veterinary bacterial and mycoplasmal infections.