624-81-7Relevant articles and documents
Method for manufacturing ammonia-N
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Paragraph 0095; 0098, (2018/12/01)
PROBLEM TO BE SOLVED: To provide a method for producing an N-alkyl hydroxylamine, which produces a pure N-alkyl hydroxylamine in a high yield under a mild condition by a simple method, does not require a strict time management and is advantageous for industrial-scale production. SOLUTION: The method for producing an N-alkyl hydroxylamine includes bringing an N-alkyl nitro compound into contact with a hydrogen source in the presence of a solid catalyst supporting palladium on silica and in the absence of a significant quantity of a fourth reaction component. The method for producing an N-alkyl hydroxylamine includes bringing (A) an N-alkyl nitro compound into contact only with (B) a hydrogen source and (C) a solid catalyst supporting palladium on silica, or bringing (A) an N-alkyl nitro compound into contact only with (B) a hydrogen source, (C) a solid catalyst supporting palladium on silica and (D) a solvent that does not deactivate catalytic activity and has a pKa of ≥12. COPYRIGHT: (C)2012,JPOandINPIT
The influence of preliminary treatment of Pt-Rh catalysts on their activity in transformations of nitroethane
Grishina, T. M.,Meshcheryakova, E. V.
, p. 727 - 729 (2007/10/02)
The electrochemical reduction of nitroethane on electrochemically deposited Pt-Rh catalysts subjected to preliminary treatment under different conditions has been studied.The greatest increase in the specific activity of the electrochemical reduction as a result of the treatment is observed for rhodium and its alloys.