6296-84-0Relevant articles and documents
Oxidation of alkenes to 1,2-diols: FT-IR and UV studies of silica-supported sulfonic acid catalysts and their interaction with H2O and H 2O2
Maggi, Raimondo,Martra, Gianmario,Piscopo, Calogero Giancarlo,Alberto, Gabriele,Sartori, Giovanni
, p. 19 - 28 (2012)
Supported sulfonic acids can be employed as efficient catalysts in the dihydroxylation of 1-methylcyclohexene with aqueous hydrogen peroxide, without the use of additional solvents, under mild condition. The reaction was deeply studied in terms of catalys
Selective Isomerization via Transient Thermodynamic Control: Dynamic Epimerization of trans to cis Diols
Macmillan, David W. C.,Oswood, Christian J.
supporting information, p. 93 - 98 (2022/01/03)
Traditional approaches to stereoselective synthesis require high levels of enantio- and diastereocontrol in every step that forms a new stereocenter. Here, we report an alternative approach, in which the stereochemistry of organic substrates is selectivel
Straightforward Synthesis of Fluorinated Enals via Photocatalytic α-Perfluoroalkenylation of Aldehydes
Wulkesch, Christian,Czekelius, Constantin
, p. 7425 - 7438 (2021/06/21)
(Per)fluorinated substances represent an important compound class with regard to drug design and material chemistry. We found a mild, operationally simple, and inexpensive photocatalytic perfluoroalkenylation reaction giving tetrasubstituted, highly electron-deficient enals straight from aldehydes. This one-step reaction tolerates various functional groups and can be applied to a wide range of substrates giving the products in yields of 52-84%.