63330-91-6Relevant academic research and scientific papers
Synthesis of organosilatranes via rhodium(I)-catalyzed silylation of organic iodides with hydrosilatrane
Murata, Miki,Yamasaki, Hiroyuki,Uogishi, Kota,Watanabe, Shinji,Masuda, Yuzuru
, p. 2944 - 2946 (2007)
The silylation of aryl and alkenyl iodides with hydrosilatrane in the presence of a rhodium(I) catalyst and DABCO provides the corresponding organosilatranes in good yield. The same catalyst system also enables the related coupling of hydrogermatrane. Georg Thieme Verlag Stuttgart.
1-Styrylsilatrane
Stradiotto, Mark,Crowe, Grant,Ruffolo, Ralph,Brook, Michael A.
, p. 637 - 639 (1997)
The structure of (E)-1-(2-phenylethenyl)-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane, C14H19NO3Si, has been determined by X-ray analysis. The N-Si dative bond length of 2.127 (4) A is in agreement with structural trends found for such systems. The C atoms linked to the N atom are disordered, an effect which has been observed in other silatrane structures.
Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins-mechanistic considerations
Frackowiak, Dawid,Marciniec, Bogdan,Sztorch, Bogna
, p. 33 - 36 (2020/03/31)
We have developed a new effective route for obtaining (E)-vinyl-substituted silatranes via ruthenium-catalyzed silylative coupling of 1-allylsilatrane with olefins. Experimental research allowed us also to propose the mechanism of the process based on sto
