6397-70-2

Basic information

• Product Name: 1-Butanone, 3-hydroxy-1,3-diphenyl-
• CAS NO: 6397-70-2
• Molecular Formula: C16H16O2
• Molecular Weight: 240.302
• Mol File: 6397-70-2.mol
• Article Data: 42

Chemical Properties

• CAS DataBase Reference: 1-Butanone, 3-hydroxy-1,3-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Butanone, 3-hydroxy-1,3-diphenyl-(6397-70-2)
• EPA Substance Registry System: 1-Butanone, 3-hydroxy-1,3-diphenyl-(6397-70-2)

Safety Data

• Hazardous Substances Data: 6397-70-2(Hazardous Substances Data)

Usage

Type of compound

Ketone and phenol derivative

Use in industry

Synthesis of pharmaceuticals, building block for organic chemical reactions, intermediate in production of polymers and resins

Medicinal properties

Potential anti-inflammatory and antioxidant effects

Applications

Chemical and pharmaceutical industries

Upstream product

• 120-46-7 1,3-diphenylpropanedione 
• 74-88-4 methyl iodide 
• 98-86-2 acetophenone 
• 96-22-0 pentan-3-one 
• 13735-81-4 1-styrenyloxytrimethylsilane 
• 111874-55-6 1,3-diphenyl-3-(trimethylsilyloxy)butan-1-one 
• 78485-07-1 3,5-diphenyl-3-methyl-1,2-dioxolane 
• 78485-08-2 3,5-diphenyl-3-methyl-1,2-dioxolane 
• 1052762-47-6 lithium 1-phenylethenolate 
• 100-58-3 phenylmagnesium bromide 
• 93-91-4 1-phenylbutan-1,3-dione 
• 693-03-8 n-butyl magnesium bromide 
• 100-52-7 benzaldehyde 
• 600-22-6 pyruvic acid methyl ester 

Downstream Products

• 54435-79-9 (E)-1,3-diphenyl-3-methyl-2-propen-1-one 
• 612-96-4 2-Phenylquinoline 
• 948-65-2 2-phenyl-indole 
• 4212-33-3 2-(2-nitrophenyl)-1-phenylethanone 
• 98-86-2 acetophenone 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 1533-20-6 1,3-diphenylbutane-1-one 
• 1609566-51-9 3-azido-1,3-diphenylbutan-1-one 
• 19804-64-9 trans-(3-methyl-3-phenyloxiran-2-yl)(phenyl)methanone 
• 19804-64-9 cis-(3-methyl-3-phenyloxiran-2-yl)(phenyl)methanone 
• 74097-59-9 (+/-)-(4S,5R)-4,5-dihydro-5-methyl-3,5-diphenyl-1-tosyl-1H-pyrazol-4-ol 
• 74097-67-9 (+/-)-(4S,5S)-4,5-dihydro-5-methyl-3,5-diphenyl-1-tosyl-1H-pyrazol-4-ol 
• 98-85-1 1-Phenylethanol 
• 13307-69-2 2,4-diphenylpentane-2,4-diol 

Relevant articles and documents

Asymmetric carbon-carbon bond forming reactions catalysed by metal(II) bis(oxazoline) complexes immobilized using supported ionic liquids

A series of bis(oxazoline) metal(II) complexes has been supported on silica and carbon supports by non-covalent immobilisation using an ionic liquid. The catalytic performance of these solids was compared for the enantioselective Diels-Alder reaction between N-acryloyloxazolidinone and cyclopentadiene and the Mukaiyama-aldol reaction between methyl pyruvate and 1-methoxy-1- trimethylsilyloxypropene. In both reactions the enantioselectivity was strongly influenced by the choice of support displaying enantioselectivies (ee values) up to 40% higher than those conducted under homogeneous reaction conditions.

Unprecedented alkylation of silicon enolates with alcohols via carbenium ion formations catalyzed by tin hydroxide-embedded montmorillonite

The solid acid, tin hydroxide-embedded montmorillonite, catalyzes the unprecedented alkylation of various silicon enolates with primary, secondary and tertiary benzylic alcohols as well as secondary allylic alcohols. The acid catalysis of Sn-Mont was not only higher than that of the other ion-exchanged montmorillonites (M-Mont; M?=?H, Ti, Fe and Al), but also higher than that of the typical homogeneous acid catalysts such as BF3·OEt2, TMSOTf and TfOH.

One-Pot Synthesis of β,β-Disubstituted α,β-Unsaturated Carbonyl Compounds

TiCl4-promoted aldol reaction of ketones as aldol acceptors followed by elimination of the titanoxy group from the Ti-aldolates affords β,β-disubstituted α,β-unsaturated carbonyl compounds in a one-pot procedure. The use of additives, such as DMF, N,N,N′,N′-tetramethylethylenediamine, and pyridine, in the elimination step was found to be important.