63972-14-5

Basic information

• Product Name: Silane, dimethyl(3-methyl-2-butenyl)phenyl-
• CAS NO: 63972-14-5
• Molecular Formula: C13H20Si
• Molecular Weight: 204.387
• Mol File: 63972-14-5.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Silane, dimethyl(3-methyl-2-butenyl)phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, dimethyl(3-methyl-2-butenyl)phenyl-(63972-14-5)
• EPA Substance Registry System: Silane, dimethyl(3-methyl-2-butenyl)phenyl-(63972-14-5)

Safety Data

• Hazardous Substances Data: 63972-14-5(Hazardous Substances Data)

Upstream product

• 78-79-5 isoprene 
• 1191-16-8 3-methylbut-2-enyl acetate 
• 115-18-4 2-methyl-3-buten-2-ol 
• 1145-98-8 1,2-diphenyltetramethyldisilane 
• 556-82-1 3-methyl-2-buten-1-ol 
• 768-33-2 phenyldimethylsilyl chloride 
• 3839-31-4 dimethyl(phenyl)silyl lithium 
• 105902-61-2 3-methylbut-2-en-1-yl phenylcarbamate 
• 91076-08-3 bis(dimethylphenylsilyl)zinc 
• 513-35-9 2-methyl-but-2-ene 
• 766-77-8 Dimethylphenylsilane 
• 3839-31-4 dimethyl(phenyl)silyllithium 
• 598-25-4 Dimethylallene 
• 75-89-8 2,2,2-trifluoroethanol 

Downstream Products

• 766-77-8 Dimethylphenylsilane 
• 94286-53-0 (2-methyl-3-buten-2-yl)dimethylphenylsilane 
• 18410-34-9 3-(dimethylphenylsilyl)-1,1-dimethyl-1-propanol 
• 120196-18-1 1-dimethyl(phenyl)silyl-3-methylbutan-2-ol 
• 83039-89-8 methyl 3-methyl-2-(dimethylphenylsilyl)-3-butenoate 
• 140-29-4 phenylacetonitrile 
• 83039-84-3 3-methyl-2-(dimethylphenylsilyl)-3-butenoic acid 

Relevant articles and documents

Silylcupration of 1,3-dienes followed by an electrophilic trapping reaction

(matrix presented) Silylcupration reaction of 1,3-dienes with a cyanocuprate reagent, PhMe2SiCuCNLi, followed by an electrophilic trapping has been reported for the first time. The use of allylic phosphates as electrophiles resulted in a highly

Palladium-catalyzed allylic C-OH functionalization for efficient synthesis of functionalized allylsilanes

A new method is described for palladium-catalyzed allylic silylation using allylic alcohols and disilanes as precursors. The reactions proceed smoothly under mild and neutral conditions, and this method is suitable for synthesis of regioand stereodefined allylsilanes. The presented silylation reaction can be easily extended to include synthesis of allylboronates by change of the dimetallic reagent. The presented synthetic procedure offers a broad platform for the selective synthesis of functionalized allyl metal reagents, which are useful precursors in advanced organic chemistry and natural product synthesis.

Practical synthesis of allylic silanes from allylic esters and carbamates by stereoselective copper-catalyzed allylic substitution reactions

The first copper-catalyzed allylic substitution reactions of allylic acetates and carbamates employing a bis(triorganosilyl)zinc reagent are reported. This novel procedure avoids the use of stoichiometric amounts of copper salts which are usually mandatory with this chemistry. Application of this methodology to standard model substrates substantiates a high diastereoselectivity for the double bond geometry (E:Z) as well as the relative configuration (syn:anti).