64101-67-3

Basic information

• Product Name: Ethanone, 1-[4-[[(4-methylphenyl)sulfonyl]oxy]phenyl]-
• CAS NO: 64101-67-3
• Molecular Formula: C15H14O4S
• Molecular Weight: 290.34
• Mol File: 64101-67-3.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[4-[[(4-methylphenyl)sulfonyl]oxy]phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[4-[[(4-methylphenyl)sulfonyl]oxy]phenyl]-(64101-67-3)
• EPA Substance Registry System: Ethanone, 1-[4-[[(4-methylphenyl)sulfonyl]oxy]phenyl]-(64101-67-3)

Safety Data

• Hazardous Substances Data: 64101-67-3(Hazardous Substances Data)

Upstream product

• 4124-41-8 p-toluenesulfonylanhydride 
• 99-93-4 4-Hydroxyacetophenone 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 92-91-1 biphenyl-4-acetaldehyde 
• 1403603-14-4 4-(2-(dimethylamino)-2-oxoacetyl)phenyl 4-methylbenzenesulfonate 
• 3263-07-8 4-(prop-1-en-2-yl)phenyl 4-methylbenzenesulfonate 
• 38430-55-6 ethyl-4-acetylbenzoate 
• 35294-37-2 1-(4-(thiophen-2-yl)phenyl)ethanone 
• 52807-17-7 4-acetyl-2'-methoxybiphenyl 
• 20412-18-4 1-[4-[(E)-2-(4-methoxyphenyl)vinyl]phenyl]ethanone 
• 1443-80-7 4-cyanophenyl methyl ketone 
• 1198088-66-2 toluene-4-sulfonic acid 4-(2-guanidino-thiazol-4-yl)-phenyl ester hydrobromide 
• 449190-86-7 1-(4-(cyclohexyloxy)phenyl)ethan-1-one 
• 171364-81-1 1-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)ethanone 
• 107558-16-7 1-(4-((4-nitrophenyl)thio)phenyl)ethanone 
• 71348-24-8 methyl (2E)-3-(4-acetylphenyl)acrylate 
• 20488-43-1 4-acetyl-trans-stilbene 

Relevant articles and documents

ProPhenol Derived Ligands to Simultaneously Coordinate a Main-Group Metal and a Transition Metal: Application to a Zn?Cu Catalyzed Reaction

A new bifunctional ligand bearing chiral N-heterocyclic carbene (NHC) and prolinol moieties is presented. Utilizing the designed ligand, an in situ formed Cu/Zn hetero-bimetallic complex unlocks the asymmetric allylic alkylation reactions of allyl phosphates with zinc keto-homoenolates, leading to the formation of various γ-vinyl ketones with good regio- and enantio-selectivity. DF sT calculation supports that the chelation of allyl phosphates with catalyst promotes the SN2’ addition and the ligand-substrate steric interactions account for the stereoselective outcome.

Phosphorylation of Alkenyl and Aryl C-O Bonds via Photoredox/Nickel Dual Catalysis

A phosphorylation of alkenyl and aryl C-O bonds at room temperature via photoredox/nickel dual catalysis is reported. By starting from easily available and inexpensive sulfonates, a variety of important alkenyl phosphonates and aryl phosphine oxides are g

Copper-Catalyzed C-S Bond Formation via the Cleavage of C-O Bonds in the Presence of S8 as the Sulfur Source

Useful and applicable methods for one-pot and odorless synthesis of unsymmetrical and symmetrical diaryl sulfides via C-O bond activation are presented. First, a new efficient procedure for the synthesis of unsymmetrical sulfides using the cross-coupling reaction of phenolic esters such as acetates, tosylates, and triflates and with arylboronic acid or triphenyltin chloride as the coupling partners is reported. Depending on the reaction, S 8 /KF or S 8 /NaO t -Bu system is found to be an effective source of sulfur in the presence of copper salts and in poly(ethylene glycol) as a green solvent. Then, the synthesis of symmetrical diaryl sulfides from phenolic compounds by using S 8 as the sulfur source and NaO t -Bu in anhydrous DMF at 120 °C under N 2 is described. By these protocols, the synthesis of a variety of unsymmetrical and symmetrical sulfides become easier than the available protocols in which thiols and aryl halides are directly used for the preparation of the sulfides.