64248-49-3Relevant articles and documents
Experimental and computational studies on the [3,3]- and [3,5]-sigmatropic rearrangements of acetoxycyclohexadienones: A non-ionic mechanism for acyl migration
Sharma, Shikha,Rajale, Trideep,Cordes, David B.,Hung-Low, Fernando,Birney, David M.
, p. 14438 - 14447 (2013/10/21)
Flash vacuum pyrolysis studies of substituted 6-acetoxy-2,4- cyclohexadienones (3 and 10) from 300 to 500 C provide strong experimental evidence that direct [3,5]-sigmatropic rearrangements in these molecules are favored over the more familiar [3,3]-sigma