6471-66-5

Basic information

• Product Name: benzyl nonan-1-oate
• Synonyms: Pelargonic acid benzyl ester;Einecs 229-316-9;Nonanoic acid, phenylmethyl ester;benzyl nonan-1-oate;Nonanoic acid benzyl ester;BENZYL NONANOATE
• CAS NO: 6471-66-5
• Molecular Formula: C₁₆H₂₄O₂
• Molecular Weight: 248.36056
• EINECS: 229-316-9
• Mol File: 6471-66-5.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 328.7°C at 760 mmHg
• Flash Point: 109.1°C
• Appearance: /
• Density: 0.963g/cm³
• Vapor Pressure: 0.000186mmHg at 25°C
• Refractive Index: 1.49
• CAS DataBase Reference: benzyl nonan-1-oate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl nonan-1-oate(6471-66-5)
• EPA Substance Registry System: benzyl nonan-1-oate(6471-66-5)

Safety Data

• Hazardous Substances Data: 6471-66-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H24O2/c1-2-3-4-5-6-10-13-16(17)18-14-15-11-8-7-9-12-15/h7-9,11-12H,2-6,10,13-14H2,1H3

Upstream product

• 111-66-0 oct-1-ene 
• 104-57-4 benzyl formate 
• 111-65-9 octane 
• 201230-82-2 carbon monoxide 
• 100-51-6 benzyl alcohol 
• 2495-35-4 benzylacrylate 
• 638-45-9 1-Iodohexane 
• 13389-42-9 trans-2-Octene 
• 111-67-1 2-octene 
• 100-52-7 benzaldehyde 
• 112-05-0 nonanoic acid 
• 1731-84-6 nonanoic acid methyl ester 
• 100-39-0 benzyl bromide 
• 28867-76-7 benzaldehyde benzylidenehydrazone 

Relevant articles and documents

Visible-light-initiated manganese-catalyzed Giese addition of unactivated alkyl iodides to electron-poor olefins

Herein, we report a mild protocol for direct visible-light-initiated Giese addition of unactivated alkyl iodides to electron-poor olefins (Michael acceptors) with catalysis by decacarbonyl dimanganese, Mn2(CO)10, an inexpensive earth-abundant-metal catalyst. This protocol is compatible with a wide array of sensitive functional groups and has a broad substrate scope with regard to both the alkyl iodide and the Michael acceptor.

Oxidative Alkane C?H Alkoxycarbonylation

Directly utilizing a chemical feedstock to construct valuable compounds is an attractive prospect in organic synthesis. In particular, the combination of C(sp3)?H activation and oxidative carbonylation involving alkanes and CO gas is a promising and efficient method to synthesize carbonyl derivatives. However, due to the high C?H bond dissociation energy and low polarity of unactivated alkanes, the carbonylation of unactivated C(sp3)?H bonds still remains a great challenge. In this work, we introduce a palladium-catalyzed radical oxidative alkoxycarbonylation of alkanes to prepare numerous alkyl carboxylates. Various alkanes and alcohols were compatible, generating the desired products in up to 94 % yield. Remarkably, ethane, a constituent of natural gas, could be employed as a substrate under the standard reaction conditions. Preliminary mechanistic studies revealed a probable palladium-catalyzed radical process.

PROCESS FOR PREPARING ESTERS FROM FORMATES AND OLEFINICALLY UNSATURATED COMPOUNDS

The invention provides a process for preparing esters from formates and olefinically unsaturated compounds with catalysts based on palladium compounds. In addition, the invention discloses a polyphasic reaction mixture and nonyl methyl ester mixtures prepared by the process according to the invention.