65231-11-0Relevant academic research and scientific papers
Experimental Evidence for a Temperature Dependent Transition between Normal and Inverse Equilibrium Isotope Effects for Oxidative Addition of H 2 to Ir(PMe2Ph)2(CO)Cl
Janak, Kevin E.,Parkin, Gerard
, p. 13219 - 13224 (2003)
The equilibrium isotope effect (EIE) for oxidative addition of H 2 and D2 to Ir(PMe2Ph)2(CO)Cl has been measured over a large temperature range, thereby demonstrating that the inverse (1) at high temperature (>90 °C). The temperature dependence of the EIE for oxidative addition of H2 and D2 to Ir(PH 3)2(CO)Cl has been calculated using the geometry and vibrational frequencies obtained from DFT (B3LYP) calculations on Ir(PH 3)2(CO)ClH2 and Ir(PH3) 2(CO)ClD2, and is in accord with the experimentally observed transition from an inverse to normal EIE for oxidative addition of H2 and D2 to Ir(PMe2Ph)2(CO)Cl: the EIE is calculated to be inverse between 0 and 510 K, reach a maximum value of 1.15 at 867 K and then slowly decrease to unity as the temperature approaches infinity. This deviation from simple van't Hoff behavior, and the occurrence of a maximum in the EIE, is the result of the entropy term being temperature dependent. At low temperature, the enthalpy term dominates and the EIE is inverse, whereas at high temperatures the entropy term dominates and the EIE is normal. The observation of both normal and inverse EIEs for the same system indicate that inferences pertaining to the magnitude of an isotope effect at a single temperature may require more detailed consideration than previously realized.
