65842-37-7

Upstream product

• 102197-61-5 Se-phenyl (4-methoxyphenyl)-oxomethanesulfenoselenoate 
• 2179-79-5 phenyl selenocyanate 
• 100-09-4 4-methoxybenzoic acid 
• 1666-13-3 diphenyl diselenide 
• 100-07-2 4-methoxy-benzoyl chloride 
• 4848-71-9 trimethylstannyl phenyl selenide 
• 794-94-5 p-Methoxybenzoic anhydride 
• 4231-69-0 1-(4-methoxybenzoyl)-1H-1,2,3-benzotriazole 
• 201230-82-2 carbon monoxide 
• 696-62-8 para-iodoanisole 
• 591-50-4 iodobenzene 
• 108-86-1 bromobenzene 
• 123-11-5 4-methoxy-benzaldehyde 
• 41924-21-4 phenyl tributylstannyl selenide 

Downstream Products

• 5739-38-8 1-(4-methoxyphenyl)-3-phenylpropan-1-one 
• 91541-28-5 4-(4-Methoxy-phenyl)-3-methyl-4-oxo-butyric acid methyl ester 
• 52754-68-4 1-(4-methoxy-phenyl)-nonan-1-one 
• 123-11-5 4-methoxy-benzaldehyde 
• 126790-44-1 methyl 2-<(1S^*,2S^*,3R^*)-3-(4'-methoxybenzoyl)-2-(methoxycarbonyl)cyclopentyl>acetate 
• 119924-83-3 phenylmethyl 4-(4-methoxyphenyl)-4-oxobutanoate 
• 119924-78-6 2-[2-(4-Methoxy-phenyl)-2-oxo-ethyl]-pentanedioic acid dibenzyl ester 
• 85234-21-5 1-(4-methoxyphenyl)but-3-en-1-one 
• 119924-80-0 4-(4-Methoxy-phenyl)-4-oxo-2-trimethylsilanyloxy-butyric acid methyl ester 
• 55234-56-5 4-(4-methoxy-phenyl)-4-oxo-butyronitrile 
• 5447-74-5 methyl 3-(4-methoxybenzoyl)propionate 
• 119924-81-1 2-[2-(4-Methoxy-phenyl)-2-oxo-ethyl]-pentanedioic acid dimethyl ester 
• 5750-10-7 4-(4-methoxy-phenyl)-2-methyl-4-oxo-butyric acid methyl ester 
• 119924-79-7 2-[2-(4-Methoxy-phenyl)-2-oxo-ethyl]-2,4-dimethyl-pentanedioic acid dimethyl ester 

Relevant academic research and scientific papers

Palladium-Catalyzed Carbonylative Synthesis of Aryl Selenoesters Using Formic Acid as an Ex Situ CO Source

A new catalytic protocol for the synthesis of selenoesters from aryl iodides and diaryl diselenides has been developed, where formic acid was employed as an efficient, low-cost, and safe substitute for toxic and gaseous CO. This protocol presents a high functional group tolerance, providing access to a large family of selenoesters in high yields (up to 97%) while operating under mild reaction conditions, and avoids the use of selenol which is difficult to manipulate, easily oxidizes, and has a bad odor. Additionally, this method can be efficiently extended to the synthesis of thioesters with moderate-to-excellent yields, by employing for the first time diorganyl disulfides as precursors.

Synthesis of selenol esters via the reaction of acyl chlorides with diselenides in the presence of Zn dust catalyzed by CoCl2·6H2O

A practical and efficient approach for the synthesis of selenol and thiol esters is described via the reaction of acyl chlorides with diselenides or disulfides in the presence of Zn dust catalyzed by inexpensive CoCl2·6H2O This proto

Nickel-Catalyzed Intramolecular Decarbonylative Coupling of Aryl Selenol Esters

This report describes a method for Ni-catalyzed intramolecular decarbonylative coupling, which enables the conversion of areneselenol esters to diaryl selenides. The inexpensive and readily available catalyst can be employed under mild reaction conditions for the construction of structurally diverse diaryl selenides, including heterocyclic and natural product derivatives. (Figure presented.).

General, Mild, and Metal-Free Synthesis of Phenyl Selenoesters from Anhydrides and Their Use in Peptide Synthesis

A mild, practical, and simple procedure for phenyl selenoesters synthesis from several anhydrides and diphenyl diselenide was developed. This transition-metal-free method provides a straightforward entry to storable Fmoc-amino acid selenoesters which are effective chemoselective acylating reagents. An application to oligopeptide synthesis was illustrated.

Syntheses of selenoesters through C-H selenation of aldehydes with diselenides under metal-free and solvent-free conditions

A DTBP-promoted C-H selenation of aldehydes with diselenides under metal-free and solvent-free conditions is described. This system shows good functional group compatibility, functional groups including bromo, trifluoromethyl, chloro, amine and heterocycle-containing moieties including thiophene and furan are all tolerated by the reaction conditions employed. Both diaryl and dialkyl diselenides reacted smoothly with aldehydes to provide selenoesters in good to excellent yields. This journal is

Syntheses of selenoesters through C-H selenation of aldehydes with diselenides under metal-free and solvent-free conditions

A DTBP-promoted C-H selenation of aldehydes with diselenides under metal-free and solvent-free conditions is described. This system shows good functional group compatibility, functional groups including bromo, trifluoromethyl, chloro, amine and heterocycle-containing moieties including thiophene and furan are all tolerated by the reaction conditions employed. Both diaryl and dialkyl diselenides reacted smoothly with aldehydes to provide selenoesters in good to excellent yields. This journal is

Syntheses of thiol and selenol esters by oxidative coupling reaction of aldehydes with RYYR (Y = S, Se) under metal-free conditions

Thiol and selenol esters were synthesized by a direct oxidative coupling reaction of aldehydes with disulfides or diselenides in ethyl acetate under metal-free conditions. Among the oxidants examined, tert-butyl peroxide (TBP) was shown to give the best results. For the substrates with both electron-donating and electron-withdrawing substituents, the reaction proceeded smoothly and gave moderate to good yields. Compared with the previous method, the present route is very simple, atom-economical and environmentally friendly. This journal is the Partner Organisations 2014.

Acylation of diselenides and disulfides with N-acylbenzotriazoles promoted by SmI2

The acylation of diselenides or disulfides with N-acylbenzotriazoles mediated by SmI2 has been achieved successfully without the presence of HMPA, and the corresponding selenolesters or thioesters have been prepared in good yields.

Ionic liquid/PPh3 promoted cleavage of diphenyl disulfide and diselenide: A straight-forward metal-free one-pot route to the synthesis of unsymmetrical sulfides and selenides

A metal-free cleavage of diphenyl disulfide and diphenyl diselenide has been achieved using ionic liquid/triphenyl phosphine (PPh3) and a convenient protocol for the one-pot synthesis of unsymmetrical sulfides and selenides by condensing 'in situ' generated thiolate or selenate anion with alkyl halides has been developed. In addition, 1,4-conjugate addition of the generated thiolate anions to activated alkenes has also been demonstrated. The ionic liquid, 1-methyl-3-pentyl imidazolium bromide, [pmIm]Br plays a crucial role in promoting the course of the reactions and shows superior activity and selectivity compared to other solvents. The [pmIm]Br has been reused for at least five times without appreciable loss of activity.

Investigation on the se-acylation with N-acylbenzotriazoles

The acylation of Se-nucleophiles with N-acylbenzotriazoles was investigated. Samarium phenylselenolate and benzylselenolate (RSeSmI 2) reacted with N-aroyl and N-alkanoylbenzotriazoles smoothly and afforded the corresponding selenol esters in g