65854-92-4

Basic information

• Product Name: Propanamide, N-(2-bromophenyl)-2,2-dimethyl-
• CAS NO: 65854-92-4
• Molecular Formula: C11H14BrNO
• Molecular Weight: 256.142
• Mol File: 65854-92-4.mol
• Article Data: 30

Chemical Properties

• CAS DataBase Reference: Propanamide, N-(2-bromophenyl)-2,2-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Propanamide, N-(2-bromophenyl)-2,2-dimethyl-(65854-92-4)
• EPA Substance Registry System: Propanamide, N-(2-bromophenyl)-2,2-dimethyl-(65854-92-4)

Safety Data

• Hazardous Substances Data: 65854-92-4(Hazardous Substances Data)

Upstream product

• 3282-30-2 pivaloyl chloride 
• 615-36-1 2-bromoaniline 
• 75-98-9 Trimethylacetic acid 
• 62-53-3 aniline 
• 6625-74-7 N-pivaloylaniline 

Downstream Products

• 959855-32-4 2-tert-butyl-1-phenyl-1H-benzimidazole 
• 1028592-37-1 (E)-3-(2-pivaloylaminophenyl)acrylic acid ethyl ester 
• 1028592-39-3 (E)-3-(2-pivaloylaminophenyl) acrylic acid 
• 146140-95-6 2-pivaloylaminophenyl boronic acid 
• 195372-65-7 N-(2-bromo-4-chlorophenyl)pivalamide 
• 54696-03-6 2-tert-butyl-1,3-benzoxazole 
• 6625-74-7 N-pivaloylaniline 
• 64414-11-5 N-(2-hydroxyphenyl)-2,2-dimethylpropionamide 
• 139058-24-5 2,2-dimethyl-N-<2-(prop-2-enyl)phenyl>propanamide 
• 137092-40-1 N-(2-bromophenyl)-2,2-dimethylpropanethioamide 
• 134031-37-1 (E)-4-<1-(((triisopropylsilyl)oxy)methyl)-1-propenyl>-1-<1-(2-trimethylacetamido)benzoyl>cyclopentene 
• 351002-89-6 1-(2-amino-5-phenyl)-2,2,2-trifluoroethanone 

Relevant articles and documents

Pd-Catalyzed Carbonylative Synthesis of 4H-Benzo[d][1,3]Oxazin-4-Ones Using Benzene-1,3,5-Triyl Triformate as the CO Source

A facile synthesis of 4H-benzo[d][1,3]oxazin-4-one derivatives by Pd-catalyzed carbonylative cross-coupling between N-(ortho-bromoaryl)amides and benzene-1,3,5-triyl triformate (TFBen) was developed. This procedure does not require the toxic and flammable gas CO as the carbonyl source and tolerates a wide scope of functional groups. Remarkably, 4H-benzo[d][1,3]oxazin-4-ones incorporated to natural products and drugs can be constructed by this method.

Novel and efficient heterogeneous polymer supported copper catalyst for synthesis of 2-substituted Benzoxazoles from 2-Haloanilides

A novel polymer supported copper complex is prepared by the immobilization of copper iodide on chemically modified polyacrylonitrile and its application in heterogeneous catalysis is described. The catalyst was prepared by easy method via synthetic modification of Polyacrylonitrile (PAN) using ethylene diamine followed by the complexation with CuI. After characterization, this complex was explored as a green and efficient heterogeneous catalyst for the synthesis of 2-benzoxazoles from 2-haloanilides. The reaction was performed without adding additional ligand and the catalyst shows activity over a broad range of substrates with quantitative product yields. The catalyst was easily recovered by simple filtration and reused successfully for further cycle.

Nickel(II)- And Silver(I)-Catalyzed C-H Bond Halogenation of Anilides and Carbamates

ortho -C-H bond halogenation of anilides and N -aryl carbamates using easily available N -halosuccinimides (NXS) as the active halogenation reagent in the presence of nickel or silver catalyst has been developed. This method provides a new approach to 2-haloanilides and carbamates, which may serve as starting materials for the synthesis of pharmaceutically and biologically active compounds.