6714-00-7

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 71, p. 3165, 1949 DOI: 10.1021/ja01177a065Tetrahedron Letters, 21, p. 3199, 1980 DOI: 10.1016/S0040-4039(00)77444-2

InChI:InChI=1/C7H12O/c1-3-4-5-6-7(2)8/h3-4H,5-6H2,1-2H3/b4-3+

Upstream product

• 101-84-8 diphenylether 
• 25456-01-3 1-methylprop-2-enyl 3-oxobutanoate 
• 3916-64-1 hepta-3,5-dien-2-one 
• 4784-77-4 (E/Z)-crotyl bromide 
• 6407-36-9 N-isopropyliden-cyclohexyl amine 
• 29149-74-4 2-acetyl-hex-4-enoic acid ethyl ester 
• 108-24-7 acetic anhydride 
• 97675-09-7 pent-3-enylmagnesium bromide 
• 141-97-9 ethyl acetoacetate 
• 591-97-9 1-chloro-2-butene 
• 123-54-6 acetylacetone 
• 4894-61-5 trans-but-2-enyl chloride 
• 67-64-1 acetone 

Downstream Products

• 123-76-2 levulinic acid 
• 110-43-0 n-pentyl methyl ketone 
• 52390-72-4 2-Heptanol 
• 13311-76-7 5-Hepten-2-ol 
• 75-07-0 acetaldehyde 
• 813-19-4 bis(tri-n-butyltin) 
• 99080-64-5 2--hept-5-en 
• 626-96-0 4-oxopentanal 

Relevant academic research and scientific papers

Asymmetric synthesis of a highly functionalized bicyclo[3.2.2]nonene derivative

The stereoselective Diels-Alder reaction between an optically active 1,4-dimethylcycloheptadiene and acrolein was effectively promoted by TBSOTf to produce a bicyclo[3.2.2]nonene derivative bearing two quaternary carbons. Seven additional transformations from the obtained bicycle delivered the C 2-symmetric bicyclo[3.3.2]decene derivative, a key intermediate in our synthetic study of ryanodine.

Semivolatile and volatile compounds in combustion of polyethylene

The evolution of semivolatile and volatile compounds in the combustion of polyethylene (PE) was studied at different operating conditions in a horizontal quartz reactor. Four combustion runs at 500 and 850°C with two different sample mass/air flow ratios and two pyrolytic runs at the same temperatures were carried out. Thermal behavior of different compounds was analyzed and the data obtained were compared with those of literature. It was observed that α,ω-olefins, α-olefins and n-paraffins were formed from the pyrolytic decomposition at low temperatures. On the other hand, oxygenated compounds such as aldehydes were also formed in the presence of oxygen. High yields were obtained of carbon oxides and light hydrocarbons, too. At high temperatures, the formation of polycyclic aromatic hydrocarbons (PAHs) took place. These compounds are harmful and their presence in the combustion processes is related with the evolution of pyrolytic puffs inside the combustion chamber with a poor mixture of semivolatile compounds evolved with oxygen. Altogether, the yields of more than 200 compounds were determined. The collection of the semivolatile compounds was carried out with XAD-2 adsorbent and were analyzed by GC-MS, whereas volatile compounds and gases were collected in a Tedlar bag and analyzed by GC with thermal conductivity and flame ionization detectors.