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Benzopyrans - XXXIII. Cycloaddition of N,N-Dimethylhydrazones and Anils of 2-Unsubstituted and 2-Methyl-4-oxo-4H-1-benzopyran-3-carboxaldehyde with N-Phenylmaleimide
Ghosh, Chandra Kanta,Bhattacharya, Kaberi,Ghosh, Chandreyi
, p. 4905 - 4912 (1994)
The chromone derivatives 1, 2, and 4 give with N-phenylmaleimide the cycloadducts 5, 12, and 13 which are converted by palladised charcoal into 2-azaxanthone 6, xanthones 14 and 15, respectively.Treatment of the azaxanthone 5 with acidic ethanol produces a mixture of salicyloyl-pyridines 7-9.
