67206-31-9Relevant academic research and scientific papers
Reaktivitaet des Silaethens Me2Si=C(SiMe3)2: Thermolyse von (Me3Si)2(Me2XSi)CLi (X z. B. (PhO)2PO2) in Anwesenheit von Silaethen-Faengern
Wiberg, Nils,Preiner, Gerhard,Schieda, Oswald
, p. 3518 - 3532 (2007/10/02)
Silaethene Me2Si=C(SiMe3)2 (1), generated as a reaction intermediate by the thermal elimination of LiX from Me2XSi-CLi(SiMe3)2, combines with the reactants a - b (e. g.Me3Si-Cl, Me3Si-OMe) with insertion in the a - b bond, with a = b - c - H (e. g.CH2=CMe
Erzeugung und Nachweis des Silaethens Me2Si=C(SiMe3)2: Thermischer Zerfall von (Me3Si)2(Me2XSi)CLi (X z. B. Hal, OR, SR)
Wiberg, Nils,Preiner, Gerhard,Schieda, Oswald,Fischer, Gerd
, p. 3505 - 3517 (2007/10/02)
Thermal decomposition of Me2XSi-CLi(SiMe3)2 (1,LiX) in diethyl ether at -102 to 10 deg C leads under intramolecular LiX-elimination (X = Hal, TosO, Ph2POn, PhS) to 1,3-disilacyclobutane 2 (2).The reactive intermediate product is the silae
