67319-03-3

Usage

InChI:InChI=1/C9H12N4O/c1-12-5-3-10-8(12)7(14)9-11-4-6-13(9)2/h3-7,14H,1-2H3

Upstream product

• 616-47-7 1-methyl-1H-imidazole 
• 13750-81-7 N-methyl-2-imidazolcarboxaldehyde 
• 109-94-4 formic acid ethyl ester 

Downstream Products

• 111410-35-6 {Fe₄O₂(bis(N-methylimidazol-2-yl)carbinol)2(bis(N-methylimidazol-2-yl)carbinolate)2(O₂CPh)4}Cl₂*5H₂O*2CH₃CN 
• 56-34-8 tetraethylammonium chloride 
• 554-68-7 triethylamine hydrochloride 
• 7647-14-5 sodium chloride 
• 193748-37-7 RuH(CO)(C₉H₁₂N₄O)(P(C₆H₅)3)2⁽¹⁺⁾*Cl^(1-) = [RuH(CO)(C₉H₁₂N₄O)(P(C₆H₅)3)2]Cl 

Relevant academic research and scientific papers

Synthesis of Novel Ruthenium Complexes Containing Bidentate Imidazole-based Ligands

Ruthenium(II) complexes containing the bidentate imidazole-based ligands (MeN2H2C3)2CO L1, (MeN2H2C3)2CHOH L2 and (MeN2H2C3)2CH2 L3 (where 1-MeN2H2C3 = 1-methylimidazol-2-yl), 1>Cl 1, 2>Cl 2 and 3>Cl 3, were synthesized by the reaction of L1-L3 with in toluene.The complexes were characterised by NMR spectroscopy and the crystal structures of 1>BF4 4 and 2>OH 5 determined.

Synthesis of Ketones and Methanols Containing Pyridinyl and N-Methylimidazolyl Groups

N-Methylimidazolyllithium reacts with N-methylimidazole-2-carboxaldehyde to form bis(N-methylimidazol-2-yl)methanol, and with the esters ethyl N-methylimidazole-2-carboxylate and ethyl pyridine-2-carboxylate to give bis(N-methylimidazol-2-yl)methanone, (mim)2CO, and (N-methylimidazol-2-yl)(pyridin-2-yl)methanone, (Py)(mim)CO, respectively.The ketones react with N-methylimidazolyllithium to give tris(N-methylimidazol-2-yl)methanol, (mim)3COH, and bis(N-methylimidazol-2-yl)(pyridin-2-yl)methanol, (Py)(mim)2COH, respectively.