67364-88-9

Basic information

• Product Name: p-(tert-butyl)benzyl acetate
• Synonyms: p-(tert-butyl)benzyl acetate;1-(Acetoxymethyl)-4-tert-butylbenzene;4-(1,1-Dimethylethyl)benzenemethanol acetate;Acetic acid 4-tert-butylbenzyl ester;Acetic acid, p-(tert-butyl)benzyl ester;Benzenemethanol, 4-(1,1-dimethylethyl)-, 1-acetate;Benzenemethanol, 4-(1,1-dimethylethyl)-, acetate;Einecs 266-669-8
• CAS NO: 67364-88-9
• Molecular Formula: C₁₃H₁₈O₂
• Molecular Weight: 206.28082
• EINECS: 266-669-8
• Mol File: 67364-88-9.mol
• Article Data: 36

Chemical Properties

• Boiling Point: 265.8°C at 760 mmHg
• Flash Point: 97°C
• Appearance: /
• Density: 0.987g/cm³
• Vapor Pressure: 0.00898mmHg at 25°C
• Refractive Index: 1.491
• CAS DataBase Reference: p-(tert-butyl)benzyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: p-(tert-butyl)benzyl acetate(67364-88-9)
• EPA Substance Registry System: p-(tert-butyl)benzyl acetate(67364-88-9)

Safety Data

• Hazardous Substances Data: 67364-88-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H18O2/c1-10(14)15-9-11-5-7-12(8-6-11)13(2,3)4/h5-8H,9H2,1-4H3

Upstream product

• 98-51-1 4-tert-butyltoluene 
• 64-19-7 acetic acid 
• 877-65-6 p-tert-butylbenzyl alcohol 
• 1058648-72-8 4-tert-butyl-1-[(ethoxymethoxy)methyl]benzene 
• 108-24-7 acetic anhydride 
• 1058648-68-2 4-tert-butyl-1-(methoxymethoxy)methyl benzene 
• 141-78-6 ethyl acetate 
• 4393-06-0 1-Phenyl-2-propen-1-ol 
• 32857-63-9 4-t-butylphenylacetic acid 
• 142-71-2 copper diacetate 
• 98-88-4 benzoyl chloride 
• 75-36-5 acetyl chloride 
• 939-97-9 4-tert-Butylbenzaldehyde 
• 127-09-3 sodium acetate 

Relevant articles and documents

Bu 4 NI-Catalyzed C-C Bond Cleavage and Oxidative Esteri??cation of Allyl Alcohols with Toluene Derivatives

A novel oxidative esterification of 1-arylprop-2-en-1-ols with toluene derivatives catalyzed by tetrabutylammonium iodide (TBAI) is reported. The optimization of the reaction conditions illustrates that each of experiment parameters including the catalyst, solvent, and oxidant is significant for present oxidative functionalization. This metal-free protocol has a broad substrate scope including the halogen groups for further functionalization and enriches the reactivity profile of allyl alcohol and toluene derivatives. In addition, this protocol represents a new transformation of allyl alcohol involving C-C bond cleavage and C-O bond forming.

Application of Yttrium Iron Garnet as a Powerful and Recyclable Nanocatalyst for One-Pot Synthesis of Pyrano[2,3-c]pyrazole Derivatives under Solvent-Free Conditions

The application of yttrium iron garnet (YIG) superparamagnetic nanoparticles as a new recyclable and highly efficient heterogeneous magnetic catalyst for one-pot synthesis of pyrano[2,3-c]pyrazole derivatives under solvent-free conditions, as well as etherification and esterification reactions are described. The advantages of the proposed method include the lack of organic solvents, clean reaction, rapid removal of the catalyst, short reaction times, excellent yields, and recyclability of the catalyst.

A General Catalytic Method for Highly Cost- and Atom-Efficient Nucleophilic Substitutions

A general formamide-catalyzed protocol for the efficient transformation of alcohols into alkyl chlorides, which is promoted by substoichiometric amounts (down to 34 mol %) of inexpensive trichlorotriazine (TCT), is introduced. This is the first example of a TCT-mediated dihydroxychlorination of an OH-containing substrate (e.g., alcohols and carboxylic acids) in which all three chlorine atoms of TCT are transferred to the starting material. The consequently enhanced atom economy facilitates a significantly improved waste balance (E-factors down to 4), cost efficiency, and scalability (>50 g). Furthermore, the current procedure is distinguished by high levels of functional-group compatibility and stereoselectivity, as only weakly acidic cyanuric acid is released as exclusive byproduct. Finally, a one-pot protocol for the preparation of amines, azides, ethers, and sulfides enabled the synthesis of the drug rivastigmine with twofold SN2 inversion, which demonstrates the high practical value of the presented method.