68820-01-9Relevant academic research and scientific papers
Regioselective ring-opening of aziridines with diselenides and disulfides using the Zn/AlCl3 system
Movassagh, Barahman,Morovat, Elaheh Salehi
experimental part, p. 117 - 122 (2012/01/04)
An efficient Zn/AlCl3-promoted highly regioselective one-pot procedure has been demonstrated for the synthesis of β-amino selenides and sulfides from a variety of diselenides/disulfides and aziridines by reductive cleavage of Se-Se and S-S bond
One-pot synthesis of β-amino/β-hydroxy selenides and sulfides from aziridines and epoxides
Ganesh, Venkataraman,Chandrasekaran, Srinivasan
experimental part, p. 3267 - 3278 (2010/02/27)
Diaryl disulfides and diselenides undergo facile cleavage on treatment with rongalite (sodium hydroxymethanesulfinate) to generate the corresponding thiolate and selenolate species in situ, which effect the ring opening of aziridines and epoxides in a reg
Pyrrolidines from olefins via radical cyclization
Gupta, Vijay,Besev, Magnus,Engman, Lars
, p. 2429 - 2432 (2007/10/03)
2,4-Disubstituted N-tosylpyrrolidines were prepared from olifeins via N- tosylaziridination, benseneselenolate ring-opening and reductive radical cyclization. Azidoselenation of olefins, followed by reduction, N-tosylation, N-allylation and reductive radical cyclization, afforded 3,4-disubstituted N- tosylpyrrolidines.
Amidoselenation of Olefins Using p-Toluenesulfonamide as a Nitrogen Nucleophile
Toshimitsu, Akio,Kusumoto, Takehiro,Oida, Tatsuo,Tanimoto, Shigeo
, p. 2148 - 2152 (2007/10/02)
The reaction of olefins, benzeneselenenyl chloride, and p-toluenesulfonamide in the presence of zinc(II) chloride affords N--p-toluenesulfonamides in good to excellent yields.When combined with alkylation on the carbon atom bearing the phenylseleno group thus introduced and subsequent oxidative or reductive removal of the selenium moiety, this reaction can be utilized in the preparation of a wide range of allylic or saturated amides.
