68820-12-2

Basic information

• Product Name: 7-Azabicyclo[4.1.0]heptane, 7-[(4-Methylphenyl)sulfonyl]-
• Synonyms: 7-Azabicyclo[4.1.0]heptane, 7-[(4-Methylphenyl)sulfonyl]-;7-tosyl-7-azabicyclo[4.1.0]heptane
• CAS NO: 68820-12-2
• Molecular Formula: C₁₃H₁₇NO₂S
• Molecular Weight: 251.34458
• Mol File: 68820-12-2.mol
• Article Data: 88

Chemical Properties

• Melting Point: 55-56 °C
• Boiling Point: 386.0±35.0 °C(Predicted)
• Appearance: /
• Density: 1.257±0.06 g/cm3(Predicted)
• PKA: -6.46±0.20(Predicted)
• CAS DataBase Reference: 7-Azabicyclo[4.1.0]heptane, 7-[(4-Methylphenyl)sulfonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 7-Azabicyclo[4.1.0]heptane, 7-[(4-Methylphenyl)sulfonyl]-(68820-12-2)
• EPA Substance Registry System: 7-Azabicyclo[4.1.0]heptane, 7-[(4-Methylphenyl)sulfonyl]-(68820-12-2)

Safety Data

• Hazardous Substances Data: 68820-12-2(Hazardous Substances Data)

Upstream product

• 127-65-1 chloroamine-T 
• 110-83-8 cyclohexene 
• 144-86-5 N-chloro-4-methylbenzenesulfonamide 
• 1338062-05-7 4-methyl-N-[(2-propoxyphenyl)-λ³-iodanylidene]benzenesulfonamide 
• 76475-12-2 N-(2-chlorocyclohexyl)-4-methylbenzenesulfonamide 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 7080-50-4 chloramine T trihydrate 
• 1058-14-6 N-p-tolylsulfonylphosphine imide 
• 21849-40-1 dibromamine-T 
• 98-59-9 p-toluenesulfonyl chloride 
• 71996-32-2 N-(5λ⁴-dibenzo[b,d]thiophen-5-ylidene)-4-methylbenzenesulfonamide 
• 286-18-0 7-azabicyclo[4.1.0]heptane 
• 70-55-3 toluene-4-sulfonamide 
• 286-20-4 cyclohexane-1,2-epoxide 

Downstream Products

• 132161-94-5 (+/-)-trans-N-(2-cyano-cyclohexyl)-4-methyl-benzene sulfonamide 
• 68820-01-9 2-(phenylselanyl)-N-tosylcyclohexanamine 
• 57981-18-7 N-cyclohex-2-enyl-4-methyl-benzenesulfonamide 
• 70-55-3 toluene-4-sulfonamide 
• 128894-19-9 3-(benzylidene)cyclohexene 
• 57981-19-8 4-methyl-N-(2-methylenecyclohexyl)benzenesulfonamide 

Relevant articles and documents

Make It Green: Copper-Catalyzed Olefin Aziridination in Water with an Iminoiodonane

The copper complex Tp(CF3)2,BrCu(NCMe) efficiently catalyses the aziridination of olefins in water using PhI=NTs as the nitrene source, with identical activity than that observed when using dichloromethane as the solvent, under the same experim

Ni-Catalyzed Carboxylation of Aziridines en Route to β-Amino Acids

A Ni-catalyzed reductive carboxylation of N-substituted aziridines with CO2 at atmospheric pressure is disclosed. The protocol is characterized by its mild conditions, experimental ease, and exquisite chemo- and regioselectivity pattern, thus unlocking a new catalytic blueprint to access β-amino acids, important building blocks with considerable potential as peptidomimetics.

Is the Electrophilicity of the Metal Nitrene the Sole Predictor of Metal-Mediated Nitrene Transfer to Olefins? Secondary Contributing Factors as Revealed by a Library of High-Spin Co(II) Reagents

Recent research has highlighted the key role played by the electron affinity of the active metal-nitrene/imido oxidant as the driving force in nitrene additions to olefins to afford valuable aziridines. The present work showcases a library of Co(II) reage