6888-71-7Relevant academic research and scientific papers
A synthetic strategy for switching the single ion anisotropy in tetrahedral Co(II) complexes
Vaidya, Shefali,Upadhyay, Apoorva,Singh, Saurabh Kumar,Gupta, Tulika,Tewary, Subrata,Langley, Stuart K.,Walsh, James P. S.,Murray, Keith S.,Rajaraman, Gopalan,Shanmugam, Maheswaran
, p. 3739 - 3742 (2015)
Four novel mononuclear tetrahedral cobalt(ii) complexes containing exocyclic mesoionic ligands of molecular formulae [CoII(L1)(X)2(MeCN)] X = Cl (1) or Br (2) and [CoII(L2)(X)2(MeCN)], X = Cl (3) or Br (4) have been reported. It is found that simple substitution of L1 (O donor in 1 and 2) by L2 (S donor in 3 and 4) results in switching of the single ion magnetic anisotropy parameter (D) from positive to negative, with a significant change in magnitude.
In situ generation of 2,3-diaryltetrazolinlidenes: Trapping experiments and ring opening to 1-cyanoazimines
Lowack, Rainer H.,Weiss, Robert
, p. 333 - 338 (2007/10/02)
The redox system formazanide ion/tetrazolium ion, realized as an ECE sequence, is as a to manipulate both electron-deficient and -surplus centers attached to the of electronically. In order to introduce this redox substituent as a nucleophilic entity into
